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70-92 Boston Street - Supplemental Site Investigation Summary Report - Data Summary Pack - November 2005 MITKENI CORPORATION "Environmental Testing For The New Millennium" July 26, 2045 TRC Solutions, Inc. 116 John Street Lowell, MA 01852 Attn: Ms. Liz Denly RE: Client Project: Flynn-Tan, Salem, Aqueous Samples Lab Project #: D0751 Dear Ms. Denly: Enclosed please find the data report of Ithe required-analyses for the samples associated with the above referenced project. If you have any questions regarding this report, please call me. We appreciate your business.. S' cer y I Edward A. Lawler Laboratory Operations Manager I j j 175 Metro Center Boulevard • Warwick, Rhode Island 02886-1755 (401) 732-3400 • Fax (401) 732-3499 • wwwmitkem.com 1 Data-S umunary Pack Analytical Data Package for TRC Solutions, Inc_ I Client Project: Flynn-Tan, Salem, Aqueous Samples s Mitkem Project ID: D0751 1 i July 26, 2005 1 Prepared For: TRC Solutions;Inc, 116 John Street . Lowell, MA 01852 Attn: Ms- Liz Denly. l ! Prepared By: Mitkem Corporation 175 Metro Center Boulevard Warwick, RI 02886 (401) 732-3400 I SDG Narrative Mitkem Corporation submits the enclosed data package in response to TRC Solutions' Flynn-Tan aqueous sample project. Under this deliverable, analysis results are presented for nine samples that were received on June 27, 2005 and logged in under Mitkem Work Order Number D0751. Analyses were performed per instruction in the chain of custody form and per email instructions from the client. For reference, a copy of the Mitkem Work Order form is included for cross-referencing the client sample ID.and laboratory sample ID. i The analyses were performed according to Massachusetts DEP and EPA SW-846 methods, with results presented in a Level 4 format deliverable. The following observation and/or deviations are observed for the following analyses: i 1. Volatile Organic Analyses: Samples were analyzed by Method 8260B. Surrogate standards: four surrogate standards were spiked into each analysis. Surrogate recoveries were within the MADEP and Mitkem QC limits. Mitkem's statistical QC limits listed on the surrogate report form are wider than the MADEP 70%-130% limits for d4-1,2-dichloroethane. Lab control sampleilab control sample duplicate: spike recoveries were within the MADEP 70%- 130% limits as well as the Mitkem statistical QC'limits. Lab fortified blank: a laboratory fortified blank at the 1 ug/L concentration level was analyzed to support a reduced reporting limit for vinyl chloride and 1,1-dichloroethene. Percent recoveries for both compounds were within the QC limits. Sample analysis: the following compounds had%RSD values exceeding 15% in the initial calibration: tetrahydrofuran, 2-hexanone, 1,2,4-trichlorobenzene, hexaehlorobutadiene and naphthalene. This initial calibration meets the acceptance i criteria in the MADEP CAM method document. Percent difference for 1,4-dioxane exceeded 30%in the continuing calibration verification standard V2G9181_ No other unusual occurrences were noted during sample analysis. l 2. MADEP VPH Analysis: Samples were analyzed by VPH Method 1.1. All samples were properly preserved. Surrogate standards: percent recoveries were below the QC timits on both detectors in the initial analysis of sample B-101'and on one detector in the initial analysis of sample MW- 108. These samples were reanalyzed, with improved results, although the recovery remained low on one detector for sample 13-101. The reanalyses were performed one day beyond the holding time. Lab control sample:spike recoveries were within the QC limits for the lab control sample and duplicate lab control sample. Matrix spike/matrix spike duplicate: duplicate matrix spikes were performed on sample MW-101. Percent recoveries and replicate RPD were within the QC limits. Sample analysis: no other unusual occurrences were noted during sample analysis. 3. MADEP EPH Analysis: Samples were extracted by Method 3510C, separatory funnel extraction, and analyzed by EPH Method 04/1.1. Surrogate recovery: recoveries were within the QC limits with the exception of low recovery for one surrogate in MW-101. This sample was refractionated with the same result. Laboratory control sample: spike recoveries in lab control sample were within the QC limits. Recoveries were biased low for the lower boiling point analytes'in the LCS duplicate. The LCSD was refractionated with the same results_ The low recoveries in the LCSD resulted in elevated RPD for the lower boiling compounds the C9-C 14 aliphatic analytes, naphthalene,2-methylnaphthalene and acenaphthene in the LCSD, and RPD for these same analytes plus C16, the C9-C18 Aliphatic range and fluorene. 'The low recoveries and elevated RPD are likely due to overconcentration for the LCSD only, and not due to overall method bias_ Matrix spike/matrix spike duplicate: duplicate matrix spike analyses were performed on sample MW-101. Percent recoveries were within the QC limits with the exception of low recoveries for the aliphatic compounds C.9;C10 and C12 in the MSD_ Replicate RPDs were within the QC limits_ 1 i Sample analysis: a contaminant in the EPH fractionation cartridges was present in the aliphatic and aromatic ranges. The identity of this contaminant has been confirmed by GUMS, and has been subtracted from the appropriate EPH Range results. No other unusual occurrences were noted during sample analysis. 4. Metals Analysis: T Samples were analyzed by method 6010B. Lab control sample: spike recoveries were within the QC limits. Matrix spike: matrix spike analysis was performed on sample MW-107. Spike recoveries were within the QC limits. Duplicate: duplicate analyses were performed on sample MW-107. Replicate RPDs were within the QC limits. Sample analysis: a laboratory fortified blank was analyzed for silver at the 20 ppb concentration to support reporting results to that level. Percent recovery was within the QC limits. No other unusual occurrences were noted during sample analysis. All pages in this report have been numbered consecutively,starting with the title page and ending with a page saying only"Last Page of Data Report". I certify that this data package is in compliance, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this i hardcopy data package has been authorized by.the laboratory manager or his designee, as yqWfl by the following signature. � C i Edward A. Lawler j Laboratory Operations Manager 7/26/05 I I MADEP MCP ANALYTICAL METHOD REPORT CERTIFICATION FORM Laboratory Name:— _ Projf_-Ct#7 Project Location: lP MADEP RTN': This Form provides certifications for the following data-set: (list Laboratory Sample ID Number(s)] Sec `Gtlo�kor Pd?.Sl Sample Matrices: Groundwater SoNSediment Drinking Water Other_ MCP SW-846 8260B 8151A( } 8330( 601013 7470AIIA( ) Methods Used 8270C( ) 8081A( } VPH 6020( ) 9014M 2( ) As specified in MADEP 8082( ) 8021B( ) EPH 7000 S3( ). 7196A(.) Coinperidu`n or AnaVkxd Methods. 1 List Release Tracking Nuinber(RTNk ff known 2 M-SW-846 Method 9014 or MADEP Ph (check all that ZWOY) 3 S=SW-846 Methods 7000 Series List indiv��method-and anat�yte (PAC)Metfiod An alfi'innabve response to questions A. A C and D is required for"Presumptive Certainty"status A Were all samples received by the laboratory in a conditions consistent with — that described on the Chain-of-Custody documentation for the data set? Yes Noy Were all CA/QC procedures required for the specified analytical methods) B included in this report followed, inducting the requirement to note and Yes discuss in a narrative QC data that did hot meet appropriate performance standards or guidelines? Does the data included In this report meet all the analytical requirements T C for'Presumptive Certainty". as described in Section 2.0 (a). (b). (c) and Yes o� b,(d (d)of the MADEP document CAM VII A, "Quality Assurance and Quality Control Guidelines for the Acquisition and Reporting of Analytical Data'? D VPH and EPH Methods avr Was the VPH or EPH Method conducted Les) No t without significant modifications(see Section 11.3 of Methods A response to questions E and F below Is required for"Presumptive Certainty"status E Were all anaytical UC.pedormance standards and recommendations for Yes ut the specified methods achieved? F Were resu is for all analyte-fist compourdsieleme.nts for the specified Yes Not-- rmdxx(s)reported? AN Ne 9awe re nxrst be addressed in an athaehed Envx vnrne"Laboratory case narrative. I, the undersigned,attest under the paints and pe►taldes of pequry that;based upon my personal Inquiry of those responsible for obtaining the information, the material contained in this analytical "s, to the best of M . ~edge and belief,accurate and complete. Signature: Position. Prinrted Marne: !� �!'-� �-- Date.. �~ CAM Vtt A:mv.3-2 April 2004 8885 CORPORATION Analysis Report: Volatile Petroleum Hydrocarbons. Client: TRC MA Date Collected: 6/23/05 Analysis: MADEP VPH.1.1 Date Received: 6/27/05 Client ID: MW=101 Date Analyzed: 7/7/05 Lab ID: D0751-01B . Aliquot Used for Analysis:5 ml Matrix: Aqueous Sample pH: < 2 Concentration in:ug/L Dilution Factor. 1 Reporting Target Analvtes Results Limit Benzene ND 5 Ethylbenzene ND 5 Toluene ND 5 o-Xylene ND 5. m-and p Xylenes ND 5 MTBE ND 5 .Naphthalene ND 5 QC Batch: 18923 VPH Ranges C5-C8 Aliphatics ND 100 C9-C10 Aromatics .140 100 C9-C12 Aliphatics ND 100, Surrogate Recovery(%): 2;5-Dibromotoluene(FID) 98 2,5-Dibromotoluene(PID) 87 ND= Not Detected Except where noted in the Project Narrative, all QA/QC procedures required by the VPH method were followed, and all performance/acceptance standards for the required QA/QC procedures were achieved_ No significant modifications were made to this method. =Surrogate recovery outside MA 30% range Page 1 of 1 D0751-01 B 1 I I ' M IT K ENJ CORPORAU/ Analysis Report: Volatile Petroleum Hydrocarbons Client: TRC_MA Date Collected: 6/23105 Analysis: MADEP VPH 1.1 Date Received: 6/27105 Client ID: B-101 Date Analyzed: 7/7/05 Lab ID: D0751-02B Aliquot Used for Analysis: 5 ml Matrix: . Aqueous Sample pH: <2 Concentration in: ug/L Dilution Factor. 1 Reporting Target Analvtes Results Limit Benzene ND 5 Ethylbenzene ND 5 Toluene ND 5 o-Xylene ND 5 m-and p-Xylenes ND 5 MTBE ND 5 Naphthalene ND 5 QC Balch: 18923 VPH Ranges C5-C8 Aliphatics ND lob _ C9-C10 Aromatics 120 100 C9-C12 Aliphatics ND 100 Surrogate Recovery(%): 2,5-Dibromotoluene(FID) 65' 2.5-Dibromotoluene(PID) 57' ND=Not Detected Except where noted in the Project Narrative,all QA/QC procedures required by the VPH method were followed, and all performance/acceptance standards for the required QA/QC procedures were achieved. No significant modifications were made to this method. ' =Surrogate recovery outside 706/c-130%range Page 1 of 1 D0751-02B i CORPORATION Analysis Report: Volatile Petroleum Hydrocarbons Y P Y Client: TRC MA Date Collected: 6/23/05 Analysis: MADEP VPH IA Date Received: 6/27/05 Client ID: B-101RE Date Analyzed: 7/8/05 Lab ID: D0751-02BRE Aliquot Used for Analysis:5 ml Matrix: Aqueous Sample pH: <2 Concentration in:ug/L Dilution Factor. 1 Reporting Target Analytes Results Limit Ben2ene ND 5 Ethylbenzene ND 5 Toluene ND 5 o-Xylene ND . 5 m-and p-Xylenes ND 5 MTBE ND 5 Naphthalene ND 5 QC Batch: 18955 VPH Ranges C5-C8 Aliphatics ND 100 C9-C10 Aromatics 120 100 C9-C12 Aliphatics ND 100 Surrogate Recovery(%): 2,Iv-Dibromotoluene(AD) 76 2,5-Dibromotoluene(PID) 66' ND= Not Detected Except where noted in the Project Narrative, all.QA/QC procedures required by the-VPH method were followed, and all performancelacceptance standards for the required CWQC procedures were achieved. No significant modifications were made to this method. =Surrogate recovery outside 704/6-130%range Page 1 of 1 D0751-02BRE I i RP Analysis Report: Volatile Petroleum Hydrocarbons Client TRC_MA Date Collected: 6/23/05 Analysis: MADEP VPH 1.1 Date Received:. 6/27/05 Client ID: MW-108 Date Analyzed: 7/7/05 Lab ID: D0751-06B Aliquot Used for Analysis: 5 ml Matrix: Aqueous Sample pH:<2 Concentration in:ug/L Dilution Factor. 1 Reporting Tablet Analvtes Results Limit Benzene ND 5 Ethylbenzene ND 5 Toluene ND 5 o-Xylene ND 5 m-and p-Xylenes ND 5 MTBE ND 5 Naphthalene ND 5 QC Batch: 18923 VPH Ranoes C5-C8 Aliphatics ND 10.0 C9-C10 Aromatics ND 100 C9-C12 Aliphatics ND 100 Surrogate Recovery(%): 2,5-Dibromotoluene(FID) 137' 2,5-Dibromotoluene(PID) 121 ND=Not Detected Except where noted in the Project Narrative, all QA/QC procedures required by the VPH method were followed, and all performance/acceptance standards for the required QA/QC procedures were achieved. No significant modifications were made to this method. =Surrogate recovery outside 70%-130%range Page 1 of 1 D0751-06B '-iif'_ Analysis Report: Volatile Petroleum Hydrocarbons Client: TRC MA Date Collected: 6/23105 Analysis: MADEP VPH 1.1 Date Received: 6/27/05 Client ID: MW-108RE Date Analyzed: 7/8/05 Lab ID: D0751-06BRE Aliquot Used for Analysis: 5 ml Matrix: Aqueous Sample pH: <2 Concentration in: ug/L Dilution Factor. 1 Reporting Target Analvtes Results Limit Benzene- ND 5 Ethylbenzene ND 5 Toluene ND 5 o-Xylene ND 5 m-and p-Xylenes ND 5 MTBE ND 5 Naphthalene ND 5 QC Batch: 18955 VPH Ranges C5-C8 Aliphatics ND 100 C9-C10 Aromatics ND 100 C9-C12 Aliphatics ND 100 Surrogate Recovery.(%): 2,5-Dibromotoluene(FID) 85 2,5-Dibromotoluene(PID) 72 ND= Not Detected Except where noted in the Project Narrative, all QA/OC procedures required by the VPH method were followed,and all performancelacceptance standards for the required QA/QC procedures were achieved. No significant modifications were made to this method. i=Surrogate recovery outside 701/6-130%range Pagel of 1 D0751-06BRE 1 ,Fl � � PO� Analysis Report: Volatile Petroleum Hydrocarbons Client: TRC_MA Date Collected: 6/24/05 Analysis: MADEP VPH 1.1 Date Received: 6/27/05 Client ID: MW-102 Date Analyzed: 717/05 - Lab ID: D0751-08B Aliquot Used for Analysis:5 ml Matrix: Aqueous Sample pH:<2 Concentration in: ug/L Dilution Factor: 1 Reporting Tanet Anal Results Limit Benzene ND 5 Ethylbenzene ND 5 Toluene ND 5 o-Xylene ND 5 m-and p-Xylenes ND 5 MTBE ND 5 Naphthalene ND 5 QC Batch: 18923 VPH Ranges C5-C8 Aliphatics ND 100 C9-C10 Aromatics ND 100 C9-C12 Aliphatics ND 100 Surrogate Recovery(%): 2,5-Dibromotoluene(FID) 88 2,5-Dibromotoluene(PID) 76 ND= Not Detected Except where noted in the Project Narrative, all QA/QC procedures required by the VPH method were followed, and all performance/acceptance standards for the required QA/QC procedures were achieved. No significant modifications were made to this method. '=Surrogate recovery outside 70%-130%range. Page 1 of 1 D0751-08B CORPORATION Analysis Report: Volatile Petroleum Hydrocarbons Client: TRC MA Date Collected: 6124/05 Analysis: MADEP VPH 1.1 Date Received: 6/27/05 Client ID: TB Date Analyzed: 7/8/05 Lab ID: D0751-09A Aliquot Used for Analysis: 5 ml Matrix: ' Aqueous Sample pH: <2 Concentration in: ug/L Dilution Factor. 1 Reporting Target Analytes Results Limit Benzene ND 5 Ethytbenzene ND 5 Toluene ND 5 o-Xylene ND 5 m-and p-Xylenes ND 5 MTBE ND 5 Naphthalene ND 5 QC Batch: 18955 VPH Ranges C5-C8 Aliphatics ND 100 C9-C10 Aromatics ND 100 C9-C12 Aliphatics ND 100 Surrogate Recovery(%): 2,5-Dibromotoluene(FID) 91 2,5-Dibromotoluerie(PID) 81 ND= Not Detected Except where noted in the Project.Narrative,all QA/QC procedures required by the VPH method were followed, and all performance/acceptance standards for the required QA/QC procedures were achieved. No significant modifications were made to this method. *=Surrogate recovery outside 70°/6-130%range Page 1 of 1 D0751-09A i O POR Analysis Report: Volatile Petroleum Hydrocarbons Client: TRC_MA Analysis: MADEP VPH 1.1 Client ID: VBLK4M Date Analyzed: 7/7/05 Lab ID: MB-18923 Aliquot Used for Analysis: 5 ml Matrix: Aqueous Sample pH: <2 Concentration in: ug/L Dilution Factor_ 1 Reporting Target Analvtes Results Limit Benzene ND 5 Ethylbenzene ND 5 Toluene ND 5 o-Xylene ND 5 m-and p-Xylenes ND 5 MTBE ND 5 Naphthalene ND 5 QC Batch: 18923 VPH Ranges C5-C8 Aliphatics ND 100 C9-C10 Aromatics ND 100 C9-C12 Aliphatics ND 100 Surrogate Recovery(%): 2,5-Dibromotoluene(FID) 91 2,5-Dibromotoluene(PID) 80 ND=Not Detected Except where noted in the Project Narrative, all QA/QC procedures required by the VPH method were followed, and all performance/acceptance standards for the required QA/QC procedures were achieved. No significant modifications were made to this method. *=Surrogate recovery outside 70%-130%range Page 1 of 1 D0751-MB L r__ Analysis Report: Volatile Petroleum Hydrocarbons Lab Control Summary Client: TRC_MA Matrix: Aqueous Lab ID for Blank Spike: LCSA 8923 Analysis Date for Blank Spike: 717105 Lab ID for BS Duplicate: LCSD-18923 Analysis Date for BS Duplicate: 717105 Analysis: MADEP VPH 1.1 Anal e %Recovery Blank Spike Blank Spike Duplicate RPD f%� Aliphatics: n-Pentane 82 85 4 2-Methylpentane 93 97 4 2,2,4-Trimethylpentane 94 103 9 n-Nonane 98 112 13 n-Decane 98 114 15 n-Butylcyclohexane 99 115 15 Aromatics: Benzene 82 85 4 Ethylbenzene 82 85 4 Toluene 82 85 4 o-Xylene 81 84 4 m-and p-Xylenes 82 85 4 MTBE 80 84 5 Naphthalene 71 72 1 QC Batch: 18923 Page 1 of 1 D0751-LCS 1 I t 'O i Analysis Report: Volatile Petroleum Hydrocarbons Client: TRC MA Analysis: MADEP VPH 1.1 Client ID: VBLK4P Date Analyzed: 7/8/05 Lab ID: MB-18955 Aliquot Used for Analysis: 5 ml Matrix: Aqueous Sample pH: <2 Concentration in:ug/L Dilution Factor. 1 Reporting Tarciet Analyzes Results Limit Benzene ND 5 Ethylbenzene ND 5 Toluene ND 5 o-Xylene ND 5 m-and p-Xylenes ND 5 MTBE ND 5 Naphthalene ND 5 QC Batch: 18955 VPH RancLes C5-C8 Aliphatics ND 100 C9-C10 Aromatics ND 100 C9-C12 Aliphatics ND 100 Surrogate Recovery(%}: 2,5-Dibromotoluene(FID) 90 2,5-Dibromotoluene(PID) 80 ND=Not Detected Except where noted in the Project Narrative,all QA/QC procedures required by the VPH method were followed, and all performance/acceptance standards for the required QA/QC procedures were achieved. No significant modifications were made to this method: ' =Surrogate recovery outside 70%-130% range Page 1 of 1 D0751-MB CORPORATION Analysis Report: Volatile Petroleum Hydrocarbons Lab Control Summary Client TRC MA Matrix: Aqueous Lab ID for Blank Spike: LCS-18955 Analysis Date for Blank Spike: 7/8/05 Lab ID for BS Duplicate: LCSD-18955 Analysis Date for BS Duplicate: 7/8/05 Analysis: MADEP VPH 1.1 Ana a _% Recovery Blank Spike Blank Spike Duplicate RPD Aliphatics: n-Pentane 75 81 8 2-Methylpentane 81 96 17 2,2,4-Trimethylpentane 86 104 19 n-Nonane 88 111 23 n-Decane 91 113 22 n-Butylcyclohexane 92 114 21 Aromatics: Benzene 73 84 14 Ethylbenzene 74 84 13 Toluene 74 85 14 o-Xylene 73 84 14 m-and p-Xylenes 73 85 15 MTBE 74 81 9 Naphthalene 70 73 4 QC Batch: 18955 Page 1 of 1 D0751-LCS I I MIT KE Ill ' CORPORATION Analysis Report: Volatile Petroleum Hydrocarbons Matrix Spike Summary Client: TRC MA Client ID: MW-101 Matrix: Aqueous Lab ID for Matrix Spike: D0751-01 BMS Analysis Date for Matrix Spike: 717/05 Lab ID for MS Duplicate: D0751-01 BMSD Analysis Date for MS Duplicate: 7/7/05 Analysis: MADEP VPH 1.1 % Recovery Analyte Matrix Sp ke Matrix Spike Duplicate RPD(% Aliohatics: n-Peritane 75 74 1 2-Methylpentane 86 85 1 2,2,4-Trimethylpentane 95 96 1 n-Nonane 95 96 1 n-Decane 98 92 6 n-Butylcyclohexane 91 90 1 Aromatics: Benzene 77 75 3 Ethylbenzene 79 77 2 Toluene 78 76 2 o-Xylene 80 78 2 m-and p-Xylenes 79 77 2 MTBE .81 78 4 Naphthalene 79 70 12 QC Batch: 18923 *=Recovery outside 70%-130% range Page 1 of,1 - D0751-M8/MSD Analysis Report: Extractable Petroleum Hydrocarbons Client: TRC_MA Analysis: MADEP EPH 0411.1 Date Collected:6/23/05 Client ID: MW-101 Date Received: 6/27/05 Lab ID: D0751-01A Date Extracted: 7/05/05 Matrix: Aqueous Date Analyzed:7/21/05 F1, 7/21/05 F2 Concentration in: ug/L Dilution: 1 Reporting EPH Ran{des Results Limits C9-C18 Aliphatics ND 200 C19-C36 Aliphatics 200 200 C11 -C22 Aromatics 220 100 Target Anal es Naphthalene ND 5 2-Methylnaphthalene ND 5 Acenaphthylene ND 5 Acenaphthene ND 5 Fluorene ND 5 Phenanthrene ND 5 Anthracene ND 5 - Fluoranthene ND 5 Pyrene ND 5 Benzo(a) anthracene ND 5 Chrysene ND 5 Benzo(b) Fluoranthene ND 5 Benzo(k) Fluoranthene ND 5 Benzo(a).pyrene ND 5 Indeno(1,2,3-cd) pyrene ND 5 Dibenzo(a,h)anthracene ND 5 Benzo(ghi)perylene ND 5 QC Batch: MB-18876 Surrogate Recovery: Chlorooctadecane 32% o-Terphenyl 52% 2-Fluorobiphenyl 83% 2-Bromonaphthalene 72% ND= Not Detected Except where noted in the Project Narrative, all QA/QC procedures required by the EPH method were followed, and all performance/acceptance standards for the required QA/QC procedures were achieved. EPH ranges are adjusted to exclude concentration of target and QC(surrogate)analytes. Page 1 of 1 D0751-01A i r O Analysis Report: Extractable Petroleum Hydrocarbons Client: TRC_MA Analysis: MADEP EPH 04/1.1 Date Collected:6/23/05 Client ID: B-101 Date Received: 6/27/05 Lab ID: D0751-02A Date Extracted: 7/05/05 Matrix: Aqueous Date Analyzed: 7/20/05, F1, 7/20/05 F2 Concentration in: ug/L Dilution: 1 Reporting EPH Ranges Results Limits C9-C18 Aliphatics ND -200 C19- C36 Aliphatics ND 200 C11 -C22 Aromatics 240 100 Target Analytes. Naphthalene ND 5 2-Methylnaphthalene ND 5 Acenaphthylene ND 5 Acenaphthene ND 5 Fluorene ND 5 Phenanthrene ND 5. Anthracene ND 5 Fluoranthene ND 5 Pyrene ND 5 Benzo (a) anthracene ND 5 Chrysene ND 5 Benzo (b) Fluoranthene ND 5 Benzo(k) Fluoranthene ND 5 Benzo (a) pyrene ND 5 Indeno(1,2,3-cd) pyrene ND 5 Dibenzo(a,h)anthracene ND 5 Benzo (ghi)perylene ND 5 QC Batch: MB-18876 Surrogate Recovery: Chlorooctadecane 41% o-Terphenyl 65% 2-Fluorobiphenyl 94% 2-Bromonaphthalene 81% ND= Not Detected Except where noted in the Project Narrative, all QA/QC procedures required by the EPH method were followed, and all performance/acceptance standards for the required QA/QC procedures were achieved. EPH ranges are adjusted to exclude concentration of target and QC (surrogate)analytes. Page-,1 of 1 D0751-02A Analysis Report: Extractable Petroleum Hydrocarbons Client TRC_MA Analysis: MADEP EPH 0411.1 Date Collected:6/23/05 Client ID: MW-106 Date Received:6/27/05 Lab ID: D0751-03A Date Extracted:7/05/05 Matrix Aqueous Date Analyzed:7120/05 Fl.7120/05 F2 Concentration in: ug/L Dilution: 1 Reporting EPH Rancies Results Limits C9-C18 Aliphatics 270 200 C19-C36 Aliphatics ND 200 C11 -C22 Aromatics 150 100 Target Analvtes Naphthalene ND 5 2-Methy1naphthalene ND 5 Acenaphthylene ND 5 Acenaphthene ND 5 Fluorene 8 5 Phenanthrene ND 5 Anthracene ND 5 Fluoranthene ND 5 Pyrene ND 5 Benzo(a)anthracene ND 5 Chrysene ND 5 Benzo(b)Fluoranthene ND 5 Benzo(k) Fluoranthene ND 5 Benzo(a)_pyrene ND 5' Indeno(1,2,3-cd)pyrene ND 5 Dibenzo(a,h)anthracene ND 5 Benzo(ghQ perylene ND 5 QC Batch:M6-18876 Surrogate Recovery: Chlorooctadecane 40% o-Terphenyl 66% 2-Fluorobiphenyl 93% 2-Bromonaphthalene 85% ND-- Not Detected Except where noted in the Project Narrative,all-QA/QC procedures required by the EPH method were followed,and all performancelacceptance standards for the required QA/QC procedures were achieved. EPH ranges are adjusted to exclude concentration of target and.QC(surrogate)analytes. Page 1 of 1 D0751-03A i i [M I T K E INI Analysis Report: Extractable Petroleum Hydrocarbons Client: TRC_MA Analysis: MADEP EPH 0411.1 Date Collected:6/23/05 Client ID: MW-108 Date Received: 6/27/05 Lab ID: D0751-06A Date Extracted: 7/05/05 Matrix: Aqueous Date Analyzed: 7/20/05 F1, 7/20/05 F2 Concentration in: ug/L Dilution: 1 Reporting EPH Ranges Results Limits C9-C18 Aliphatics ND 200 C19-C36 Aliphatics ND 200 C11 -C22 Aromatics ND 100 Target Analytes Naphthalene ND 5 2-Methylnaphthalene ND 5 Acenaphthylene ND 5 Acenaphthene ND 5 Fluorene ND 5 Phenanthrene ND 5 Anthracene ND 5 Fluoranthene ND 5 Pyrene ND 5 Benzo(a) anthracene ND 5 Chrysene ND 5 Benzo (b) Fluoranthene ND 5 Benzo (k) Fluoranthene ND 5 Benzo (a)pyrene ND 5 Indeno(1,2,3-cd)pyrene ND 5 Dibenzo(a,h)anthracene ND 5 Benzo (ghi)perylene ND 5 Surrogate Recovery: QC Batch: MB-18876� Chlorooctadecane 44% o-Terphenyl 65% 2-Fluorobiphenyl 85% 2-Bromonaphthalene 68% ND= Not Detected Except where noted in the Project Narrative, all QA/QC procedures required by the EPH method were followed, and all performance/acceptance standards for the required QA/QC procedures were achieved. EPH ranges are adjusted to exclude concentration of target and QC (surrogate)analytes_ Page 1 of 1 D0751-06A CORPORATION Analysis Report: Extractable Petroleum Hydrocarbons Client TRC_MA Analysis: MADEP EPH 04/1.1 Date Collected: 6124/05. Client ID: MW-104 Date Received:6/27/05 Lab ID: D0751-07A Date Extracted: 7/05/05 Matrix: Aqueous Date Analyzed: 7/20/05 F1, 7/20105 F2 Concentration in: ug/L Dilution: 1 Reporting EPH Ranges Results Limits C9-C18 Aliphatics 240 200 C19-C36 Aliphatics 220 200 C11 C22 Aromatics ND 100 Target Analytes Naphthalene ND 5 2-Methylnaphthalene ND 5 Acenaphthylene ND 5 Acenaphthene ND 5 Fluorene ND 5 Phenanthrene ND 5 Anthracene ND 5 Fluoranthene ND 5 Pyrene ND 5 Benzo (a)anthracene ND 5 Chrysene ND 5 Benzo(b) Fluoranthene ND 5. Benzo (k) Fluoranthene ND 5 Benzo (a)pyrene ND 5 Indeno(1,2,3-cd)pyrene ND 5 Dibenzo(a,h) anthracene ND 5 Benzo (ghi) perylene ND .5 QC Batch: MB-18876 Surrogate Recovery: Chlorooctadecane 52% o-Terphenyl 62% 2-Fluorobiphenyl 920/6 2-Bromonaphthalene 79% ND= Not Detected Except where noted in the Project Narrative, all QA/QC procedures required by the EPH method were followed, and all performance/acceptance standards for the required QA/QC procedures were achieved. EPH ranges are adjusted to exclude concentration of target and QC (surrogate)analytes. Page 1 of 1 D0751-07A i I - MIT KEA,% CORPORATION Analysis Report: Extractable.Petroleum Hydrocarbons Client: TRC_MA Analysis: MADEP EPH 04/1.1 Date Collected:6/24/05 Client ID: MW-102 Date Received: 6/27/05 Lab ID: DO751-08A Date Extracted: 7/05/05 Matrix: Aqueous _ Date Analyzed: 7/20/05 F1, 7/20/05 F2 Concentration in: ug/L Dilution: 1 Reporting EPH Ran(ies Results Limits C9 -C18 Aliphatics ND 200 C19- C36 Aliphatics 200 200 C11 - C22 Aromatics 100 100 Target Analytes Naphthalene ND 5 2-Methylnaphthalene ND 5 Acenaphthylene ND 5 Acenaphthene ND 5 Fluorene ND 5 -Phenanthrene ND 5 Anthracene ND 5 Fluoranthene ND 5 Pyrene ND 5 Benzo (a) anthracene ND '5 Chrysene ND 5 Benzo (b) Fluoranthene ND 5 Benzo (k) Fluoranthene ND 5 Benzo (a) pyrene ND 5 Indeno (1,2,3-cd) pyrene ND 5 Dibenzo(a,h)anthracene ND 5 Benzo (ghi)perylene ND 5 QC Batch: MB-18876 Surrogate Recovery. Chlorooctadecane 47% o-Terphenyl 56% 2-Fluorobiphenyl 88% 2-Bromonaphthalene 83% ND= Not Detected Except Where noted in the Project Narrative, all QA/QC procedures required by the EPH method were followed, and all performance/acceptance standards for the required QA/QC procedures were achieved. EPH ranges are adjusted to exclude concentration of target and QC (surrogate)analytes. Page 1 of 1 DO751-08A Analysis Report: Extractable Petroleum Hydrocarbons Client: TRC_MA Analysis: MADEP EPH 04/1.1 Date Collected: Client ID: Date Received: Lab ID: MB-18876 Date Extracted: 7/05105 Matrix: Aqueous Date Analyzed: 7/19/05 F1, 7/19/05 F2 Concentration in: ug/L Dilution: 1 Reporting EPH Ranges Results Limits C9-C18 Aliphatics ND 200 C19-C36 Aliphatics ND 200 C11 - C22 Aromatics 130 100 Target Analytes Naphthalene ND 5 2-Methylnaphthalene ND 5 Acenaphthylene ND 5 Acenaphthene ND 5 Fluorene ND 5 Phenanthrene ND 5 Anthracene ND 5 Fluoranthene ND 5 Pyrene ND 5 Benzo (a) anthracene ND 5 Chrysene ND 5 Benzo(b) Fluoranthene ND 5 Benzo (k) Fluoranthene ND 5 Benzo (a) pyrene ND 5 Indeno(1,2,3-cd) pyrene ND 5 Dibenzo(a,h) anthracene ND 5 Benzo (ghi)perylene ND 5 QC Batch: MB-18876 Surrogate Recovery: Chlorooctadecane 61% o-Terphenyl 80% 2-Fluorobiphenyl 86% 2-Bromonaphthalene 65% ND= Not Detected Except where noted in the Project Narrative, all QA/QC procedures required by the EPH method-were followed, and all performance/acceptance standards for the required QA/QC procedures were achieved. EPH ranges are adjusted to exclude concentration of target and QC(surrogate).analytes. Page 1 of 1 MB-18876 1 CORPORATION Analysis Report: Lab Control Sample Client TRC_MA Date Extracted for LCS/LCSD: 7/05/05 Matrix: Soil Date Analyzed for LCS: 7/19/05 Lab ID for Lab Control Sample(LCS): LCS-18876 Date Analyzed for LCSD: 7/20/05 Lab ID for Lab Control.Sample Duplicate(LCSD): LCSD-18876 Analysis: MADEP EPH 04-1.1 MADEP EPH - F1 - ALIPHATICS Anal e % Recovery LCS LCSD % RPD Nonane C9 42 9 126 Decane C10 55 18 101 Dodecane C12 55 22 87 Tetradecane C 14 61 33 59 Hexadecane C16 69 49 34 Octadecane C18 66 57 14 Nonadecane C19 70 64 8 Eicosane C20 71 66 8 Docosane C22 70 67 5 Tetracosane C24 73 70 4 Hexacosane C26 72 68 5 Octacosane C28 71 68 4 Triacontane C30 67 64 5 Hexatriacontane C36 72 .68 5 C9-C18 Aliphatics 58 31 59 C19-C36 Aliphatics 71 67 6 Surragate Recover LCS LCSD Chlorooctadecane 63% 56% Naphthalene Breakthrough: 0.0% 0.0% 2-Methylnaphthalene Breakthrough.- 0.0% 0.0% Page T of 2 eph_Ics CORPORATION Analysis Report: Lab Control Sample Client: TRC MA Date Extracted for LCS/LCSD: 7/05/05 Matrix: Soil Date Analyzed for LCS: 7/19/05 Lab ID for Lab Control Sample(LCS): LCS-18876 Date Analyzed for LCSD: 7/20/05 Lab ID for Lab Control Sample Duplicate(LCSD): LCSD-18876 Analysis: MADEP EPH 04-1.1 MADEP EPH - F2 -AROMATICS Anal)de % Recovery LCS LCSD % RPD Naphthalene 62 31 68 2-Methylnaphthalene 62 32 66 Acenaphthylene 65 37 55 Acenaphthene 76 45 51 Fluorene 70 45 42 Phenanthrene 74 61 20 Anthracene 73 60 20 Fluoranthene 74 67 9 Pyrene 74 67 11 Benzo(a)anthracene 70 65 7 Chrysene 78 73 7 Benzo(b) Fluoranthene 69 66 6 Benzo(k) Fluoranthene 79 73 8 Benzo(a) pyrene 70 65 8 Indeno(1,2,3-cd) pyrene 67 63 5 Dibenzo(a,h)anthracene 68 66 3 Benzo(ghi) perylene 65 61 6 C11 -C22 Aromatics 70 57 20 Surrogate Recovery LCS LCSD o-Terphenyl 76% 66% 2-Fluorobiphenyl 90% 88% 2-Bromonaphthalene 75% 56% Page 2 of 2 eph.Ics 1 I " Analysis Report: Matrix Spike Client TRC_MA Date Extracted for MS/MSD: 7/05/05 Matrix: Soil Date Analyzed for MS: 7/20105 Client ID: MW-101 Date Analyzed for MSD: 7/20/05 Lab ID for Matrix Spike (MS): D0751-01AMS Lab ID for Matrix Spike Duplicate (MSD): D0751-01AMSD Analysis: MADEP EPH 04-1.1 MADEP EPH - F1 -ALIPHATICS .Anal e % Recovery MS MSD % RPD Nonane C9 29 25 16 Decane C10 40 36 12 Dodecane C12 42 39 7 Tetradecane C14 45 45 1 Hexadecane C16 51 54 6 Octadecane C18 52 54 4 Nonadecane C19 55 57 4 Eicosane C20 56 59 6 Docosane C22 55 58 5 Tetracosane C24 57 60 5 Hexacosane C26 56 59 4 Octacosane C28 56 58 3 Triacontane C30 53 55 4 Hexatriacontane C36 59 58 0 C9-C18 Aliphatics 43 42 2 C19-C36 Aliphatics 56 58 4 Surrogate Recovery MS MSD Chlorooctadecane, 51% 49% Page 1 of 2 eph.ms/msd CORPORATION Analysis Report: Matrix Spike Client: TRC MA Date Extracted for MS/MSD: 7/05/05 Matrix: Soil Date Analyzed for MS: 7/20/05 Client ID: MW-101 Date Analyzed for MSD: 7/20105 Lab ID for Matrix Spike(MS): D0751-01AMS Lab ID for Matrix Spike Duplicate(MSD): D0751-01AMSD Analysis: MADEP EPH 04-1.1 MADEP EPH - F2 -AROMATICS Anal e % Recovery. MS MSD % RPD Naphthalene 45 40 11 2-Methylnaphthalene 59 60 3 Acenaphthylene 60 59 0 Acenaphthene 62 62 0 Fluorene 63 63 0 Phenanthrene 62 64 3 Anthracene 59 61 2 Fluoranthene 60 61 3 Pyrene 58 62 6 Benzo(a)anthracene 54 56 2 Chrysene 60 62 3 Benzo(b) Fluoranthene 53 54 2 Benzo(k)Fluoranthene 60 62 3 Benzo(a)pyrene 52 54 5 Indeno(1,2,3-cd) pyrene 49 50 3 Dibenzo(a,h)anthracene 51 51 1 Benzo(ghi) perylene 47 48 1 . C11 -C22 Aromatics 56 57 2 Surrogate Recovery_ MS MSD o-Terphenyl 61% 66% 2-Fluorobiphenyl 84% 94% 2-Bromonaphthalene 71% 84% Page 2 of 2 eph.ms/msd i 03/04/05 Fractionation Checks LOT:405101-QQ Conc Recovery Conc Recovery ALIPHATICS (ng/uL) (%) AROMATICS (ng/uL) (%) Nonane C9 10.377 83 Naphthalene 11.507 92 Decarie C10 10245 82 2-Methylnaphthalene 11.137 89 Dodecane C12 11.058 88 Acenaphthylene 11.913 95 Tetradecane C14 9.962 80 Acenaphthene 11.789 94 Hexadecane C16 10.405 83 Fluorene 11.222 90 Octadecane C18 11202 90 Phenanthrene 11.436 91 Nonadecane C19 10.431 83 Anthracene 11.497 92 Eicosane C20 10.733 86 Fluoranthene 11.246 9p Docosane C22 10.875 87 Pyrene 11.07 89 Tetracosane C24. 11.14 89 Benzo(a)anthracehe 10.139 81 Hexacosane C26 10.372 83 Chrysene 10.42 83 Octacosane C28 10.585 85 Benzo(b) Fluoranthene 8.966 72 Triacontane C30 10.747 86 Benzo(k)-Fluoranthene 9.476 76 Hexatriacontane C36 -11.859 95 Benzo(a)pyrene 8.582 69 Indeno(1,2,3-cd)Pyrene 7.124 .57 C9-C18 Aliphatics 84 Dibenzo (a,h) anthracene 7.713 62. C19-C36 Aliphatics 87 Benzo(ghi) perylene 8.138 65 C11 -C22 Aromatics 82 lA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET B-107 Lab Name: MITKEM CORPORATION Contract: Lab Code: MITKEM Case No. : SAS No'. : SDG No. : MD0751 Matrix: (soil/water) WATER Lab Sample ID: D0751-04B Sample wt/vol: 5.000 (g/mL) ML Lab File ID: V2G9195 Level: (low/med) LOW Date Received: 06/27/05 Moisture: not dec. Date Analyzed: 06/28/05 GC Column: DB-624 ID: 0.25 (mm) Dilution Factor: 1.0 Soil Extract Volume: (uL) Soil Aliquot Volume: (uL) CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q 75-71-8-=-------Dichlorodifluoromethane 5 U 74-87-3---------Chloromethane 5 U 75-01-4---------Vinyl Chloride 1 U 74-83-9---------Bromomethane 5 U 75-00-3---------Chloroe.thane 5 U 75-69-4---------Trichlorofluoromethane 5 U 75-35-4---------1;1-Dichloroethene 1 U 67-64-1---------Acetone 5 U 74-88-4----------Iodomet e 5 U 75-15-0---------Car.bon. Disulfid 5 U 75-09-2---------Methylene Chloride 5 U 156-60-5--------trans-1,2-Dichloroethene 5 U 1634-04-4-------Methyl tert-butyl ether 1 J 75-34-3---------1,1-Dichloroethene 5 U 108-05-4--------Vinyl acetate 5 U 78-93-3---------2-Butanone 5 U 156-59-2--------cis-1,2-Dichloroethene 5 U 590-20-7-------=2,2-Dichloropropane 5 U 74-97-5----------Bromochloromethane 5 U 67-66-3---------Chloroform 5 U 109-99-9--------Tetrahydrofuran 5 U 71-55-6---------1,1,1-Trichloroethane 5 U 563-58-6--------1,1-Dichloropropene 5 U 56-23=5---------Carbon Tetrachloride 5 U 107-06-2--------1,2-Dichloroethane 5 U 71-43-2---------Benzene 5 U 79-01-6---------Trichloroe ene 5 U 78-87-5---------1,2-Dichloropropane 5 U 74-95-3---------Dibromomethane 5 U 75-27-4---------Bromodichloromethane 5 U 10061-01-5------cis-1,3-Dichloropropene 5 U 108-10-1--------4-Methyl-2-pentanone 5 U 108-88-3--------Toluene 5 U 10061-02-6------trans-1,.3-Dichloropropene 5 U FORM I VOA OLM03.0 lA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET i Lab Name: MITKEM CORPORATION Contract: B-107 Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 Matrix: (soil/water) WATER Lab Sample ID: D0751-04B Sample wt/vol: 5.000 (g/mL) ML Lab File ID: V2G9195 Level: (low/med) LOW Date Received: 06/27/05 Moisture: not dec. _ Date Analyzed: 06/28/05 GC Column: DB-624 ID: 0.25 (mm) Dilution Factor: 1.0 Soil Extract Volume: (uL) Soil Aliquot Volume: (uL) CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q 79-00-5---------1,1,2-Trichloroethane 5 U 142-28-9--------1,3-Dichloropropane 5 U 127-18-4--------Tetrachloroethene 5 U 591-78-6--------2-Hexanone 5 U 124-48-1--------Dibromochloromethane 5 U 106-93-4--------1,2-Dibromoethane 5 U 108-90-7--------Chlorobenzene 18 630-20-6---=----1,1,1,2-Tetrachloroethane 5 U 100-41-4--------Euhylbenzene 5 U -------------=--m,p-Xylene 5 U 95-47-6---------o-Xylene 5 U 1330-20-7-------Xylene (Total) 5 U 100-42-5--------Styrene 5 U 75-25-2---------Bromoform 5 U 38-82-8---------Isopropylbenzene 56 79-34-5---------1,1,2,2-Tetrachloroethane 5 U 108-86-1---.-----Bromobenzene 5 U 96-18-4---------1,2,3-Trichloropropane 5 U 103-65-1--------n-Propylbenzene 68 95-49-8---------2-Chlorotoluene 5 U 108-67-8--------1,3,5-Trimethylbenzene 5 U 106-43-4--------4-Chlorotoluene 5 U 98-06-6---------tert-Butylbenzene_ 11 95-63-6---------1,2,4-Trimethylbenzene 80 135-98-8------ sec-Butylbenzene 25 99-87-6---------4-Isopropyltoluene 5 U 541-73-1--------1,3-Dichlorobenzene 1 J 106-46-7--------1,4-Dichlorobenzene 4. J 104-51-8--------n-Butylbenzene 12 95-50-1---------1,2-Dichlorobenzene 5 -U 96-12-8---------1,2-Dibromo-3-chloropropane_ 5 U 120-82-1---------1,2,4-Trichlorobenzene 5 U 87-68-3-=--------Hexachlorobutadiene 5 U 91-20-3------- --Naphthalene- 1 J FORM I VOA OLM03.0 +:�:;�, _ lA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET B-107 Lab Name: MITKEM CORPORATION Contract: Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 Matrix: (soil/water) WATER Lab Sample ID: D0751-04B Sample wt/vol: 5.000 (g/mL) ML Lab File ID: V2G9195 Level: (low/med) LOW Date Received: 06/27/05 Ow Moisture: not dec. Date Analyzed: 06/28/05 GC Column: DB-624 ID: 0.25 (mm) Dilution Factor: 1.0 Soil Extract Volume: (uL) Soil Aliquot Volume: (uL) CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q 87-61-6--------=1,2,3-Trichlorobenzene 5 U 60-29-7---------Ether 5 U 108-20-3--------Diisopropyl Ether 5 U 637-92-3--------Ethyl tert-butyl ether 5 U 994-05-8--------tert-Amyl methyl ether 5 U 123-91-1--------1,4-Dioxane 100 U FORM I VOA OLM03 .0 lA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET MW-107 Lab Name: MITKEM CORPORATION Contract: Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 Matrix: (soil/water) WATER Lab Sample ID: D0751-05B Sample wt/vol: 5.000 (g/mL) ML Lab File ID: V2G9196 Level: (low/med) LOW Date Received: 06/27/05 Moisture: not dec. Date Analyzed: 06/28/05 GC Column: DB-624 ID: 0.25 (mm) Dilution Factor: 1.0 Soil Extract Volume: _(uL) Soil Aliquot Volume: _ (uL) CONCENTRATION UNITS: CAS NO. - COMPOUND (ug/L or ug/Kg) UG/L Q 75-71-8---------Dichlorodifluoromethane 5 U 74-87-3---------Chloromethane 5 U 75-01-4---------Vinyl Chloride 1 U 74-83-9---------Bromomethane 5 U 75-00-3---------Chloroethane 5 U 75-69-4---------Trichlorofluoromethane 5 U 75-35-4---------1, 1-Dichloroethane 1 U 67-64-1---------Acetone 2 J 74-88-4---------Iodomet e 5 U 75-15-0---------Carbon Disulfide 5 U 75-09-2---------Methylene Chloride 5 U 156-60-5--------trans-1,2-Dichloroethane 5 U 1634-04-4-------Methyl tert-butyl ether 2 J 75-34-3---------1, 1-Dichloroethane 5 U -108-05-4--------Vinyl acetate 5 U 78-93-3---------2-Butanone 5 U 156-59-2--------cis-1,2=Dic oroethene 5 U 590-20=7--------2, 2-Dichloropropane 5 U 74-97-5---------Bromochloromethane 5 U 67-66-3---------Chloroform 5 U 109-99-9--------Tetrahydrofuran 5 U 71-55-6---------1,1,1-Trichloroethane 5 U 563-58-6--------1, 1-Dichloropropane 5 U 56-23-5---------Carbon Tetrachloride 5 U 107--06-2---------1,.2-Dichloroethane 5 U 71-43-2=--------Benzene 5 U 79-01-6---------Trichloroethene .5 U 78-87-5---------1,2-Dichloropropane 5 U 74-95-3---------Dibromomethane . 5 U 75-27-4---------Bromodichloromethane 5 U 10061-01-5------cis=1,3-Dichloropropene 5 U 108-10-1--------.-4-Methyl-2-pentanone 5 U 108=88-3--------Toluene 5 U 10061-02-6------trans-1,3-Dichloropropene 5 U FORM I VOA OLM03.0 IA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET MW-107 Lab -Name: MITKEM CORPORATION Contract: Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 Matrix: (soil/water) WATER Lab Sample ID: D0751-05B Sample wt/vol: 5.000 (g/mL) ML Lab File ID: V2G9196 Level: (low/med) LOW Date Received: 06/27/05 Moisture: not dec. Date Analyzed: 06/28/05 GC Column: DB-624 ID: 0.25 (mm) Dilution Factor: 1.0 Soil Extract Volume: (uL) Soil Aliquot Volume: (uL) CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L. or ug/Kg) UG/L Q 79-00-5---------1,1,2-Trichloroethane 5 U 142-28-9--------1,3-Dichloropropane 5 U 127-18-4--------Tetrachloroethene 5 U 591-78-6--------2-Hexanone 5 U 124-48-1--------Dibromochlorome e 5 U 106-93-4--------1,2-Dibromoethane 5 U 10'8-90-7--------Chlorobenzene 18 630-20-6--------1,1,1,2-Tetrachloroethane 5 U 100-41-4--------Ettylbenzene 5 U ----------------m,p-Xylene 5 U 95-47-6---------o-Xylene _ 5 U 1330-20-7-------Xylene (Total) 5 U 100-42-5--------Styrene 5 U 75-25--2---------Bromoform 5 U 98-82-8---------Isopropy nzene 57 79-34-5---------1, 1,2,2-Tetrachloroethane 5 U 108-86-1--------Bromobenzene 5 U 96-18-4---------1,2,3-Trichloropropane __ 5 U 103-65-1--------n-Propylbenzene 68 95-49-8---------2-Chlorotoluene 5 U 108-67-8--------1,3,5-Trimethy zene 5 U 106-43-4--------4-Chlorotoluene 5 U 98-06-6---------tert-Butylbenzene 11 95-63-6---------1,2,4-Trimethylbenzene 82 135-98-8--------sec-Butylbenzene 26 99-87-6---------4-Isopropyltoluene 5 U 541-73-1--------1,3-Dichlorobenzene 1 J 106-46-7--------1,4-Dichlorobenzene 4 J 104-51-8--------n-Butylbenzene 12 95-50-1---------1,2-Dichlorobenzene 5 U 96-12-8---------1,2-Dibromo-3-chloropropane 5 U 120-82-1--------1,2,4-Trichlorobenzene 5 U 87-68-3---------Hexachlorobutadiene 5 U 91-20-3---------Naphthalene . 1 J FORM I VOA OLM03. 0 lA EPA SAMPLE NO_ VOLATILE ORGANICS ANALYSIS DATA SHEET MW-107 Lab Name: MITKEM CORPORATION Contract: Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 Matrix: (soil/water) WATER Lab Sample ID: D0751-05B Sample wt/vol: 5.000 (g/mL) ML Lab File ID: V2G9196 Level: (low/med) LOW Date Received: 06/27/05 °s Moisture: not dec. Date Analyzed: 06/28/05 GC Column: DB-624 ID: 0.25 Ann) Dilution Factor: 1.0 Soil Extract Volume: (uL) Soil Aliquot Volume: (uL) CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q 87-61-6---------1,2,3-Trichlorobenzene 5 U 60-29-7---------Ether _ 5 U 108-20-3--------Diisopropyl Ether 5 U 637-92-3--------Ethyl tert-butyl ether 5 U 994-05-8--------tert-Amyl methyl ether 5 U 123-91-1--------1,4-Dioxane 100 U FORM I VOA OLM03 .0 lA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET TB Lab Name: MITKEM CORPORATION Contract: Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 Matrix: (soil/water) WATER Lab Sample ID: D0751-09A Sample wt/vol: 5.000 (g/mL) ML Lab File. ID: V2G9190 Level: (low/med) LOW Date Received: 06/27/05 s Moisture: not dec. - Date Analyzed: 06/28/05 GC Column: DB-624 ID: 0.25 (mm) Dilution Factor: 1.0 Soil Extract Volume:__ (uL) Soil Aliquot Volume: (uL) CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q 75-71-8---------Dichlorodifluoromethane 5 U 74-87-3---------Chloromethane 5 U 75-01-4---------Vinyl Chloride 1 U 74-83-9---------Bromomethane 5 U 75-00-3---------Chloroethane 5 U. 75-69-4---------Trichlorofluoromethane 5 U 75-35-4---------1, 1-Dichloroethene 1 U 67-64-1------- Acetone 5 U 74-88-4---------Iodomethane 5 U 75-15-0---------Carbon Disulfide 5 U 75-09-2---------Methylene Chloride 5 U 156-60-5--------trans-1,2-Dichloroethene 5 U 1634-04-4-------Methyl tert-butyl ether 5 U 75-34-3---------1,1-Dichloroethane 5 U 108-05-4--------Vinyl acetate 5 U 78-93-3---------2-Butanone 5 U 156-59-2--------cis-1,2-Dichloroethene 5 U 590-20-7--------2,2-Dichloropropane 5 U 74-97-5---------Bromochloromethane. 5 U 67-66-3---------Chloroform 5 U 109-99-9--------Tetrahydrofuran 5 U 71-55-6---------1,1,1-Trichloroethane 5 U 563-58-6--------1,1-Dichloropropene 5 U 56-23-5---------Carbon Tetrachloride 5 U 107-06-2--------1,2-Dichloroethene 5 U 71-43-2---------Benzene 5 U 79-01-6---------Trichloroethene 5 U 78-87-5---------1,2-Dichloropropane 5 U 74-95-3---------Dibromomethane 5 U 75-27-4----------Bromodichloromethane 5 U 10061-01-5------cis-1,3-Dichloropropene 5 U 108-10-1--------4-Methyl-2-pentanone 5 U 108-88-3------ Toluene 5 U 10061-02-6------trans-1,3-Dichloropropene 5 U FORM I VOA OLM03.0 lA EPA SAMPLE NO_ VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: MITKEM CORPORATION Contract: TB Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 Matrix: (soil/water) WATER Lab Sample ID: D0751-09A Sample wt/vol: 5.000 (g/mL) ML Lab File ID: V2G9190 Level: (low/med) LOW Date. Received: 06/27/05 Moisture: not dec. Date Analyzed: 06/28/05 GC Column: DB-624 ID: 0.25 (mm) Dilution Factor: 1.0 Soil Extract Volume:_ (uL) Soil Aliquot Volume: (uL) CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q 79-00-5---------1,1,2-Trichloroethane 5 U 142-28-9------- 1,3-Dichloropropane 5 U 127-18-4--------Tetrachloroethene 5 U 591-78-6--------2-Hexanone 5 U 124-48-1--------Dibromochloromet e 5 U 106-93-4--------1,2-Dibromoethane 5 U .108-90-7--------Chlorobenzene 5 U 630-20-6--------1, 1,1, 2-Tetrachloroethane 5 U 100-41-4--------Euhylbenzene 5 U ----------------m,p-Xylene 5 U 95-47-6---------o-Xylene 5 U 1330-20-7-------Xylene (Total 5 U 100-42-5--------Styrene 5 U 75-25-2---------Bromoform 5 U 98-82-8---------Isopropylbenzene 5 U 79-34-5---------1, 1,2,2-Tetrachloroethane 5 U 108-86-1--------Bromobenzene 5 U 96-18-4---------1,2,3-Trichloropropane 5 U 103-65-1--------n-Propylbenzene 5 U 95-49-8---------2-Chlorotoluene 5 U 108-67-8---------1,3, 5-Trimethyl nzene 5 U 106-43-4--------4-Chlorotoluene 5 U 98-06=6-------=-.tert-Butylbenzene . 5 U 95-63-6---------1,2,4-Trimethylbenzene 5 U 135-98-8--------sec-Butylbenzene 5 U 99-87-6---------4-Isopropyltoluene 5 U 541-73-1--------1,3-Dichlorobenzene 5 U 106-46-7--------1,4-Dichlorobenzene 5 U 104-51-8--------n-Butylbenzene 5. U 95-50-1---------1,2-Dichlorobenzene 5 U 96-12-8---------1,2-Dibromo-3-chloropropane_ 5 U 120-82-1--------1,2,4-Trichlorobenzene 5 U 87-68-3----=----Hexachlorobutadiene 5 U 91-20-3---------Naphthalene' 5 U FORM I VOA- OLM03.0 lA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET TB Lab Name: MITKEM CORPORATION Contract: 1. Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 Matrix: (soil/water) WATER Lab Sample ID: D0751-09A Sample wt/vol: 5.000 (g/mL) ML Lab File ID: V2G9190 Level: (low/med) LOW Date Received: 06/27/05 g Moisture: not dec. _ Date Analyzed: 06/28/05 GC Column: DB-624 ID: 0.25 (mm) Dilution Factor: 1:0 Soil Extract Volume: (uL) -Soil Aliquot' Volume: (uL) CONCENTRATION UNITS: CAS. NO. COMPOUND (ug/L or ug/Kg) UG/L Q 87-61-6---------1,2,3-Trichlorobenzene 5 U 60-29-7---------Ether 5 U 108-20-3--------Diisopropyl Ether 5 U 637-92-3--------Ethyl tert-butyl ether 5 U 994-05-8--------tert-Amyl methyl ether 5 U 123-91-1--------1,4-Dioxane 100 U FORM I VOA 0LM03.0 lA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET V2VLCS Lab Name: MITKEM CORPORATION Contract: _I ( Lab Code: MITKEM Case No. : SAS No_ : SDG No. : MD0751 Matrix: (soil/water) WATER Lab Sample ID• LCS-18759 Sample wt/vol: 5.000 (g/mL) ML Lab File ID: V2G9185 Level: (low/med) LOW Date Received: Moisture: not dec. Date Analyzed: 06/28/05 GC Column: DB-624 ID: 0.25 (mm) Dilution Factor: 1.0 Soil Extract Volume: WL) Soil Aliquot Volume: (uL) CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q 75-71-8---------Dichlorodifluoromethane 50 74-87-3---------Chloromethane 41 75-01-4---------Vinyl Chloride 45 74-83-9---------Bromomethane 43 75-00-3---------Chloroethane 46 75-69-4---------Trichlorofluoromethane 46 75-35-4---------1,1-Dichloroethene 44 67-64-1---------Acetone 56 74-88-4---------Iodomet e 58 75-15-0---------Carbon Disulfide 49 75-09-2---------Methylene Chlori e 50 156-60-5--------trans-1,2-Dichloroethene 45 1634-04-4-------Methyl tert-butyl ether 53 75-34-3---------1,1-Dichloroethane 50 108-05-4--------Vinyl acetate 46 78-93-3---------2-Butanone 47 156-59-2--------cis-1,2-Dichloroethene 46 590-20-7--------2,2-Dichloropropane 55 74-97-5---------Bromochloromethane 58 67-66-3---------Chloroform 52 109-99-9--------Tetrahydrofuran 50 71-55-6----------1,1,1-Trichloroethane 49 563-58-6--------1,1-Dichloropropene 47 56-23-5---------Carbon Tetrachloride 52 107-06-2--------1,2-Dichloroethane 56 71-43-2---------Benzene 51 79-01-6---------Trichloroethene 58 78-87-5---------1,2-Dichloropropane 49 74-95-3------=--Dibromomethane 49 75-27-4---------Bromodichloromethane 54 10061-01-5------cis-1,3-Dichloropropene 54 108-10-1--------4-Methyl-2-pentanone 45 108-88-3--------Toluene 47 10061-02-6------trans-1,3-Dichloropropene 56 FORM I VOA OLM03 .0 lA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET V2VLCS Lab Name: MITKEM CORPORATION Contract: Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 Matrix: (soil/water) WATER Lab Sample ID: LCS-18759. Sample wt/vol: 5.000 (g/mL) ML Lab File ID: V2G9185 Level: (low/med) LOW Date Received: Moisture: not dec. Date Analyzed: 06/28/05 GC Column: DB-624 ID: 0.25 (mm) Dilution Factor: 1.0 Soil Extract Volume: ___ _ (uL) Soil Aliquot Volume: (uL) CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q 79-00-5---------1,1,2-Trichloroethane 48 142-28-9--------1, 3-Dichloropropane 51 127-18-4--------Tetrachloroethene 45 591-78-6--------2-Hexanone 47 124-48-1--------Dibromochloromethane 58 106-93-4--------1,2-Dibromoethane 46 108-90-7--------Chlorobenzene 46 630-20-6--------1,1, 1,2-Tetrachloroethane 56 100-41-4--------Ethyl-benzene 42 ----------------m,p-Xylene 88 95-47-6---------o-Xylene 46 1330-20-7-------Xylene (Total)-- 130 100-42-5--------Styrene 44 75-25-2---------Bromoform 50 98-82-8---------Isopropyl nzene 44 79-34-5---------1,1,2, 2-Tetrachloroethane 43 108-86-1--------Bromobenzene 49 96-18-4---------1,2,3-Trichloropropane 48 103-65-1--------n-Propylbenzene 44 95-49-8---------2-Chlorotoluene . 46 108-67-8--------1,3,5-Trimethy nzene 40 106-43-4--------4-Chlorotoluene 47 98-06-6---------tert-Butylbenzene 45 95-63-6---------1,2,4-Trimethylbenzene 40 135-98-8--------sec-Butylbenzene 41 99-87-6---------4-Isopropyltoluene 45 541-73-1--------1,3-Dichlorobenzene 51 106-46-7--------1,4-Dichlorobenzene 49 104-51-8--------n-Butylbenzene 41 95-50-1---------1,2-Dichlorobenzene 50 96-12-8---------1,2-Dibromo-3-chloropropane 48 120-82-1--------1,2,4-Trichlorobenzene 39 87-68-3---------Hexachlorobutadiene 42 91-20-3---------Naphthalene 44 FORM I VOA OLM03.0 1A EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET V2VLCS Lab Name: MITKEM CORPORATION Contract: Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 Matrix: (soil/water) WATER Lab Sample ID: LCS-18759 Sample wt/vol: 5.000. (g/mL) ML Lab File ID: V2G9185 Level: (low/med) LOW Date Received: Moisture: not dec. Date Analyzed: 06/28/05 GC Column: DB-624 ID: 0.25 (inn) Dilution Factor: 1.0 Soil Extract Volume: (uL) Soil Aliquot Volume: (uL) CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q 87-61-6---------1,2,3-Trichlorobenzene 39 60-29-7---------Ether 45 108-20-3--------Diisopropyl Ether 43 637-92-3--------Ethyl tert-butyl ether 50 994-05-8--------tert-Amyl methyl ether 56 123-91-1--------1,4-Dioxane 990 FORM I VOA- OLM03.0 lA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET V2VLCSD Lab Name: MITKEM CORPORATION Contract: Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 Matrix: (soil/water) WATER Lab Sample ID: LCSD-18759 Sample wt/vol: 5.000 (g/mL) ML Lab File ID: V2G9186 Level: (low/med) LOW Date Received: -°s Moisture: not dec. __ Date Analyzed: 06/28/05 GC Column: DB-624 ID: 0.25 (mm) Dilution Factor: 1.0 Soil Extract Volume: (uL) Soil Aliquot Volume: (uL) CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q 75-71-8---------Dichlorodifluoromethane 51 74-87-3---------Chloromethane 42 75-01-4---------Vinyl Chloride 46 74-83-9---------Bromomethane 43 75-00-3---------Chloroethane 46 75-69-4---------Trichlorofluoromethane 40 75-35-4---------1, 1-Dichloroethene 42 67-64-1---------Acetone 53 74-88-4---------Iodomethane 57 75-15-0----------Carbon Disulfide 49 75-09-2---------Methylene Chloride 48 156-60-5----.----trans--1,2-Dichloroethene 44 1634-04-4-------Methyl tert-butyl ether 52 75-34-3---------1, 1-Dichloroethane 48 108-05-4--------Vinyl acetate 45 78-93-3---------2-Butanone 47 156-59-2--------cis-1,2-Dichloroethene 45 590-20-7--------2,2-Dichloropropane 53 74-97-5---------Bromochloromethane 57 67-66-3---------Chloroform 50 109-99-9--------Tetrahydrofuran 50 71-55-6---------1,1,1-Trichloroethane 47 563-58-6--------1,1-Dichloropropene 47 56-23-5---------Carbon Tetrachloride 50 107-06-2--------1,2-Dichloroethane 53 71-43-2---------Benzene 50 79-01-6---------Trichloroethene 55 78-87-5---------1,2-Dichloropropane 48 74-95-3---------Dibromomethane 49 75-27-4----------Bromod.ichloromethane 52 10061-01-5------cis-1,3-Dichloropropene 53 108-10-1--------4-Methyl-2-pentanone 46 108-88-3--------Toluene 47 10061-02-6------trans-1,3-Dichloropropene - 55 FORM I VOA OLM03'.0 j lA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET V2VLCSD Lab Name: MITKEM CORPORATION Contract: I Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 Matrix: (soil/water) WATER Lab Sample ID: LCSD-18759 Sample wt/vol: 5.000 (g/mL) ML Lab File ID: V2G9186 Level: (low/med) LOW Date Received: 01 Moisture: not dec. Date Analyzed: 06/28/05 GC Column: DB-624 ID: 0.25 (mm) Dilution Factor: 1.0 Soil Extract Volume: (uL) Soil Aliquot Volume: (uL) CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) 'UG/L Q 79-00-5---------1,1,2-Trichloroethane 47 142-28-9--------1,3-Dichloropropane 50 127-18-4--------Tetrachloroethene 45 591-78-6--------2-Hexanone 50 124-48-1--------Dibromochloromethane 55 106-93-4--------1, 2=Dibromoethane 46 108-90-7--------Chlorobenzene 45 630-20-6--------1,1,1,2-Tetrachloroethane 54 100-41-4--------Ethylbenzene 43 ----------------m,p-Xylene 87 95-47-6---------o-Xylene 44 1330-20-7-------Xylene (Total) 130 100-42-5--------Styrene 44 75-25-2---------Bromoform 50 98-82-8---------Isopropylbenzene 44 79-34-5-------- 1, 1,2,2-Tetrachloroethane 44 108-86-1--------Bromobenzene 48 96-18-4---------1, 2,3-Trichloropropane 49 103=65-1--------n-Propylbenzene 44 95-49-8---------2-Chlorotoluene 48 108-67-8--------1,3,5-Trimethylbenzene 40 106-43-4--------4-Chlorotoluene 47 98-06-6---------tert-Butylbenzene 44 95-63-6---------1,2,4-Trimethylbenzene 41 135-98-8--------sec-Butylbenzene 40 99-87-6---------4-Isopropyltoluene 44 541-73=1--------1, 3-Dichlorobenzene 5.0 106-46-7---------1,4-Dichlorobenzene 48 104-51-8--------n-Butylbenzene 41 95-50-1---------1,2-Dichlorobenzene 48 '96-12-8---------1,2-Dibromo-3-chloropropane_ 53 120-82-1--------1,2,4-Trichlorobenzene 41 87-68-3---------Hexachlorobutadi_ene 41 91-20-3---------Naphthalene 48 FORM I VOA OLM03 . 0 lA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET V2VLCSD Lab Name: MITKEM CORPORATION 'Contract: Lab Code: MITKEM Case No. : SAS No. : SDG No. MD0751 Matrix: (soil/water) WATER Lab Sample ID: LCSD-18759 Sample wt/vol: 5.000 (g/mL) ML Lab File ID: V2G9186 Level: (low/med) LOW Date Received: s Moisture: not dec. Date Analyzed: 06/28/05 GC Column: DB-624 ID: 0.25 (mm) Dilution Factor: 1.0 Soil Extract Volume: (uL) Soil Aliquot Volume: (uL) CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q 87-61-6---------1,2,3-Trichlorobenzene 41 60-29-7---------Ether 46 108-20-3--------Diisopropyl Ether 43 637-92-3--------Ethyl tent-butyl ether 49 994-05-8--------tert-Amyl methyl .ether 52 123-91-1--------1,4-Dioxane 1100 FORM I VOA OLM03.0 lA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: MITKEM CORPORATION Contract: V2VLFB Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 Matrix: (soil/water) WATER Lab Sample ID: LFB-18759 Sample wt/vol: 5.000 (g/mL) ML Lab File ID: V2G9184 Level: (low/med) LOW Date Received: Moisture: not dec. Date Analyzed: 06/28/05 GC Column: DB-624 ID: 0.25 (mm) Dilution Factor: 1.0 Soil Extract Volume: _(uL) Soil Aliquot Volume: (uL) CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q 75-71-8----------Dichlorodifluoromethane 0.8 J 74-87-3---------Chloromethane 0.8 J 75-01=4---------Vinyl Chloride 0.9 J 74-83-9---------Bromomethane 1 J 75-00-3---------Chloroethane 1 J 75-69-4---------Trichlorofluoromethane 1 J 75-35-4---------1,1-Dichloroethene 0.9 J 67-64-1---------Acetone 2 J 74-88-4---------Iodomet e 1 J 75-15-0---------Carbon Disulfide 0.9 J 75-09-2---------Methylene Chloride 2 J 156-60=5--------trans-1,2-Dichloroethene 5 U 1634-04-4-------Methyl tert-butyl ether 0.9 J 75-34-3---------1;1-Dichloroethane 1 J 108-05-4--------Vinyl acetate 5 U 78-93-3---------2-Butanone 1 J 156-59-2--------cis-1, 2-Dichloroethene 5 U 590-20-7--------2,2-Dichloropropane 2 J 74-97-5---------Bromochloromethane 1 J 67-66-3---------Chloroform 1 J 109-99-9------ TetrahydrolUi�a­n 5 U 71-55-6------- 1, 1,1-Trichloroethane 0.9 J 563-58-6--------1,1-Dichloropropene 5 U 56-23-5----------Carbon Tetrachloride 1 J 107-06-2--------1, 2-Dichloroethane 1 J 71-43-2---------Benzene 0.9 J 79-01-6---------Trichloroet ene 0.9 J 78-87-5---------1,2-Dichloropropane_ 0.9 J 74-95-3---------Dibromomethane_ 0.9 J 75-27-4---------Bromodichloromethane 1 J 10061-01-5------cis-1,3-Dichloropropene 0.8 J 108-10-1--------4-Methyl-2-pentanone 1 J 108-88-3--------Toluene 0.9 J 10061-02-6------trans=l,3-D1c oropropene 5 U FORM I VOA OLM03.0 lA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET V2VLFB Lab Name: MITKEM CORPORATION Contract: Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 Matrix: (soil/water) WATER Lab Sample ID: LFB-18759 Sample wt/vol: 5.000 (g/mL) ML Lab File ID: V2G9184 Level: (low/med) IOW Date Received: Moisture.: not dec. Date Analyzed: 06/28/05 GC Column: DB-624 ID: 0.25 (mm) Dilution Factor: 1.0 Soil Extract Volume: (uL) Soil Aliquot Volume: (uL) CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q 79-00-5---------1, 1,2-Trichloroethane 5 U 142-28-9--------1,3-Dichloropropane 0.9 J 127-18-4--------Tetrachloroethene 0.9 J 591-78-6--------2-Hexanone 5 U 124-48-1--------Dibromochloromethane 1 J 106-93-4-------=1,2-Dibromoethane 5 U 108-90-7--------Chlorobenzene 0.9 J 630-20-6--------1, 1,1,2-Tetrachloroethane 0.9 J 100-41-4--------Euhylbenzene 1 J ----------------m,p-Xylene 1 J 95-47-6---------o-Xylene 5 U 1330-20-7-------Xylene (Total) 1 J 100-42-5--------Styrene 5 U 75-25-2---------Bromoform 5 U 98-82-8---------Isopropyl zene 5 U 79-34-5---------1,1,2,2-Tetrachloroethane 5 U 108-86-1--------Bromobenzene 1 J 96-18-4---------1,2,3-Trichloropropane 26 103-65-1--------n-Propylbenzene 0.9 J 95-49-8---------2-Chlorotoluene 5 U 108-67-8-----.---1,3,5-Trimethylbenzene 5 U 106-43-4--------4-Chlorotoluene 5 U 98-06-6---------tert-Butylbenzene . 5 U 95-63-6---------1,2,4-Trimethylbenzene 5 U 135-98.-8--------sec-Butylbenzene 5 U 99-87-6---------4-Isopropyltoluene 0.8 J 541-73-1--------1,3-Dichlorobenzene 1 J 106-46-7--------1,4-Dichlorobenzene 1 J 104-51-8--------n-Butylbenzene 5 U 95-50-1---------1,2-Dichl:orobenzene 1 J 96-12-8---------1,2-Dibromo-3-chloropropane_ 5 U 120-82-1--------1,2,4-Trichlorobenzene 5 U 87-68-3---------Hexachlorobutadiene 5 U 91-20-3---------Naphthalene 5 U FORM I VOA OLM03.0 lA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET V2VLFB Lab Name: MITKEM CORPORATION Contract: Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 Matrix: (soil/water). WATER Lab Sample ID: LFB-18759 . Sample wt/vol: 5.000 (g/mL) ML Lab File ID: V2G9184 Level: (low/med) LOW Date Received: Moisture: not dec. Date Analyzed: 06/28/05 GC Column: DB-624 ID: 0.25 (mm) Dilution Factor: 1.0 Soil Extract Volume: (uL) Soil Aliquot Volume.: (uL) CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q. 87-61-6---------1,2,3-Trichlorobenzene 5 U 60-29-7=--------Ether 5 U 108-20-3--------Diisopropyl Ether 5 U 637-92-3--------Ethyl tert-butyl ether 5 U 994-05-8---------tert-Amyl methyl ether 5 U - 123-91-1--------1,4-Dioxane 100 U FORM I VOA OLM03.0 U.S_ EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET i { I MW-106 Lab Name: Mitkem Corporation Contract: 28367-011 Lab Code: MITKEM Case No. SAS No. : SDG No: : MD0751 Matrix (soil/water) : WATER Lab Sample ID: D0751-03 Level (low/med) : MED Date Received: 06/27/05 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L CAS No. , Analyte Concentration C i Q M 7440-36-0 Antimony _ 201iU P 7440-38-2 Arsenic 201U P 7440-39-3 Barium 2001U P 7440-41-7 Beryllium 5.0• U p 7440-43-9 Cadmium 5.0' U P 7440-47-3 Chromium 139i P 7439-92-1 !Lead l0i U P 7440-02-0 Nickel 50iU P 7782-49-2 ;Selenium _ 30:' U P 7940-22-4 'Silver _ 20U P 7440-28-0 Thallium _ 20' U P 7440-62-2 °Vanadium 50 U : I P 7440-66-6 Izinc 50U P i Comments: FORM I - IN SW846 U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET ----- B-107 Lab Name: Mitkem Corporation Contract: 28367-011 _ Lab- Code: MITKEM Case No. SAS No. : SDG No. : MD0751 Matrix (soil/water) : WATER Lab Sample ID: D0751-04 Level (low/med) : MED Date Received: 06/27/05 Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L CAS No. i Analyte Concentration , C ; Q M 7440-36-0 !Antimony 20U p 7440-38-2 !Arsenic 24.91 p 7940-39-3 Barium 200U ! p 7440-41-7 iBeryllium 5.0'. 0 p 7440-43-9 ;Cadmium 5.0° U p 7440-47-3 'Chromium 20; U P 7439-92-1 ;Lead 10 U p 7440-02-0 ;Nickel 50; U P 7782-49-2 :Selenium _ 30: U p 7440-22-4 IS 20; U I P 7440-28-0 (Thallium 20: U p 7440-62-2 'Vanadium 50 U- P 7440-66-6 jZinc 50 U p ' ' ! Comments: FORM I - IN SW846 U.S. EPA - CLP I EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW-107 Lab Name: Mitkem Corporation Contract: 28367-011 ! Lab Code: MITKEM Case No. SAS No. : SDG No. : MD0751 Matrix (soil/water) : WATER Lab Sample ID: D0751-05 Level (low/med) : MED Date Received: 06/27/05. % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L CAS No. Analyte ; Concentration CI Q M 7440-36-0 Antimony .201 U P J 7440-38-2 Arsenic _ 24.2 P 7440-39-3 Barium 2001 U P V7440-47-3 0-41-7 Beryllium 5.0 U ! P 0-43-9. Cadmium _ _ 5.01U i P Chromium 20 U P 9-92-1 Lead 10! U P 0-02-0 Nickel 501U P 82-49-2 Selenium _ 30 Ul P 7440-22-4 Silver _ 20 U P 7440-28-0 Thallium 201U ! P 7440-62-2 ,Vanadium 50! U P 7440-66-6 lZinc 50; U P Comments: FORM I - IN SW846 U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET j --- - MW-104 Lab Name: Mitkem. CorE-)oration Contract: 28367-011 i Lab Code: MITKEM Case No. SAS No. : SDG No. : MD0751 Matrix (soil/water) : WATER Lab Sample ID: D0751-07 Level (low/med) :. MED Date Received: 06/27/05 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L CAS No. i Analyte Concentration C ' Q M 7440-36-0 Antimony 20? U p 7440-38-2 ;Arsenic 21.9, p 7440-39-3 ;Barium 200U P 7440-41-7 :Beryllium S.OiU P 7440-43-9 `Cadmium 5.0; U p 7440-47-3 `:Chromium 2pjU p 7439-92-1 ;Lead lOj U p 7440-02-0 iNickel 501u P 17782-49-2 ;Selenium 30, u P , 7440-22-4 Silver 201u P '7440-28-0 :Thallium 20 U p 7440-62-2 ,Vanadium 50: u 7440-66-6 !Zinc 50; U P Comments: FORM I - IN SW846 U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW-102 Lab Name: Mitkem Corf:oration Contract: . 28367-011 Lab Code: MITKEM Case No_ SAS No. : SDG No. : MD0751 Matrix (soil/water) : WATER Lab Sample_ ID: D0751-08 Level (low/med) : MED Date Received: 06/27/05 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L CAS No. I Analyte : Concentration C Q M 7440-36-0 IAntim..y 20 U ' p 7440-38-2 JArsenic _ 20 U I p 7440-39-3 Barium _ _ 2001 U p 7440-41-7 Beryllium _ 5.O U p 7440-43-9 Cadmium 5.0 U p 7440-47-3 Chromium_ 20 U p 7439-92-1 'Lead _ 101 U _i p 7440-02-0 Nickel _ 501U i p J 7782-49-2 Selenium _ 30 U P 7440-22-4 !Silver 20 U p 7440-28-0 Thallium 20 U p 744-0-62-2 lVanadium 50 U p 7440-66-6 Zinc 50 U € P.. Comments: FORM I - IN SW846 U.S- EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET - - 1 B-107 Lab Name: Mitkem Corporation Contract: 28367-011 Lab Code: MITKEM Case No. SAS No. : SDG No. : MD0751AG Matrix (soil/water) : WATER Lab Sample ID: D0751-04 Level (low/med) : MED Date Received: 06./27/05 % Solids: 0.0 Concentration Units (ug/L or mg/kg. dry weight): UG/L CAS No. Analyte : Concentration_ C Q M 7440-22-4 silver 10i 0 : P Comments: FORM I - IN SW846 U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW-102 Lab Name: Mitkem Corporation Contract: 28367-011 _ Lab Code: MITKEM Case No. SAS No. : SDG No. : MD0751-AG Matrix (soil/water) : WATER Lab -Sample ID: D0751-08 Level (low/med) : MED Date Received: 06/27/05 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L CAS No. Analyte Concentration C Q :` M I -4 7440-22-4 Silver 10 U. P Comments: SW846 FORM I - IN U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET Mw-104 Lab Name: Mitkem Corporation Contract: 28367-011 _ Lab Code: MITKEM Case No. SAS No. : SDG No. : MD0751AG Matrix (soil/water) : WATER Lab Sample ID: D0751-07 Level (low/med) : MED Date Received: 06/27/05 % Solids:- 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L CAS No. Analyte Concentration C • Q M i7990-z2-4. Silver _ 10 U P Comments:- FORM I - IN -SW846 O.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET ; - MW-106 Lab Name: Mitkem Corporation Contract: 28367-011 Lab Code: MITKEM Case No. SAS No. : SDG No. : MD0751AG Matrix (soil/water) : WATER Lab Sample ID: D0751-03 Level (low/med) : MED- Date Received: 06/27/05 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L CAS No. i Analyte Concentration C ° Q M _ - 7440-22-4 Silver - 10 b P Comments: SW.846 FORM I - IN U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW-107 Lab Name: Mitkem_Corporation Contract: 28367-011 Lab Code: MITKEM Case "No. SAS No. : SDG No. : MD0751AG Matrix (soil/water) : WATER Lab Sample ID: D0751-05 Level (low/med) : NED Date Received: 06/27/05 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L CAS No. Analyte Concentration Ci Q M 17440_22-4 Silver 10 O P Comments: SW646 FORM I - IN U.S_ EPA - CLP 7 LABORATORY CONTROL SAMPLE Lab Name: Mitkem Corporation Contract: 28367-0110-0000 Lab Code: MITKEM Case 'No. SAS No. : SDG No. : MD0751 Solid LCS Source: Aqueous LCS Source: LCS-18824 Aqueous (ug/L) Solid (mg/kg) Analyte True Found %R True Found C Limits oR l :Antimony 455.01 443.80'. 97.5': j Arsenic 455.01 486.08 106.8 j E ;Barium 9100.0 9764 . 90 107.1 ;Beryllium 227.0; 238.40` 105.0 Cadmium 227.0. 241 .32' 106.3: :Chromium 910.0 940.45- 103.3 j .Lead 455.0: 485.32 106.7- -Nickel 2270.0 2407.48° 106.1 i Selenium 455.0` 465.40; 102.3: :Silver 1130.0` 1091_ 31_ 96.6 Thallium 455.0 477.03: 104.8 .Vanadium 2270.0' 2381.85 104 .9 ;Zinc 2270.0! 2380.54� 104 .9 FORM VII - IN SW846 U.S_ EPA - CLP 7 LABORATORY FORTIFIED BLANK Lab Name: Mitkem Corporation Contract• 28367-0110-0000 Lab Code: MITKEM Case No_ SAS No_ : SDG No MD0751 Solid LCS Source: Aqueous LCS Source: LFB-18824 i Aqueous (ug/L) Solid (mg/kg) Analyte True Found %R True Found C Limits %R (Silver�::] 20.OI 19. 67! 98.9 --- - _-�--' FORM VII - IN SW846 U.S. EPA - CLP 7 LABORATORY CONTROL SAMPLE Lab Name: Mit_ kem Cor oration Contract: 28367-0110-0000 Lab Code: MITKEM Case No. SAS No.: SDG No. : MD0751AG Solid LCS Source: Aqueous LCS Source: LCS-18824 Solid (mg/kg) --- Aqueous (ug/L) Limits %R Analyte True Found %R True Found C ii Silver 1208.361106.9 FORM VII - IN 8W846 U.S. EPA - CLP 7 LABORATORY FORTIFIED BLANK Lab Name: Mitkem Corporation Contract: 28367-0110-0000 Lab Code: MITKEM Case No. SAS No. : SDG No. : MD0751 Solid LCS Source: Aqueous LCS Source: LFB-18824 Aqueous (ug/L) Solid (mg/kg) Analyte True Found %R True Found C Limits %R Silver .10.01 10.131101.3 FORM VII _ IN SW846, 2A WATER VOLATILE SYSTEM MONITORING COMPOUND RECOVERY Lab Name: MITKEM CORPORATION Contract: Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 EPA SMCl SMC2 SMC3 OTHER TOT SAMPLE NO. # (DCE)# (TOL)# (BFB)# OUT --- ------ ------ ------ --- 01 VBLK2V 106 94 88 78 0 02 V2VLFB 101 92 84 74 0 03 V2VLCS 102 90 85 89 0 04 V2VLCSD 100 90 85 90 0 05 TB 106 92 84 84 0 06 B-107 111 97 82 95 0 07 MW-107 106 93 82 86 0 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 QC LIMITS SMCl = Dibromofluoromethane (78-117) SMC2 (DCE) = 1,2-Dichloroethane-d4 (62-124) SMC3 (TOL) = Toluene-d8 (81-116) OTHER(BFB) = Bromofluorobenzene (74-126) # Column to be used to flag recovery values * Values outside of contract required QC limits page 1 of 1 FORM II VOA-1 OLM03.0 FORM 3 WATER VOLATILE LAB CONTROL SAMPLE Lab Name: MITIEI CORPORATION Contract: Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 Matrix Spike Sample No. : V2VLCS SPIKE SAMPLE LCS LCS QC. ADDED CONCENTRATION CONCENTRATION % LIMITS COMPOUND (ug/L) (ug/L) (ug/L) REC ## REC. Dichlorodifluoromethane 50 '50 100 48-135 Chloromethane . 50 41 82 60-118 .Vinyl Chloride 50 45 90 65-113 Bromomethane 5b 43 86 73-122 Chloroethane 50 46 92 72-118 Trichlorofluoromethane 50 46 92 68-129 1,1-Dichloroethene 50 44 88 67-121 Acetone 50 56 112 38-161 Iodomethane 50 58 116 72-130 Carbon Disulfide 50 49 98 53-137 Methylene Chloride 50 50 100 59-132 trans-1,2-Dichloroethen 50 45 90 71-124 Methyl tert-butyl ether 50 53 106 75-123 1,1-Dichloroethane 50 50. 100 83-116 Vinyl acetate. 50 46 92 44-160 2-Butanone50 47 94 64-139 cis-1, 2-Dichloroethene 50 46 92 83-120 2, 2-Dichloropropane 50 55 110 70-129 Bromochloromethane 50 58 116 85-124 Chloroform 50 52 104 89-118 Tetrahydrofuran - 50 - 50- 100 76-126 1, 1,1-Trichloroethane 50 49 98 81-122 1, 1-Dichloropropene 50 47 94 76-122 Carbon Tetrachloride 50 52 104 79-125 1,2-Dichloroethane 50 56 112 83-123 Benzene 50 51 102 81-120 Trichloroethene 50 58 116 77-121 1, 2-Dichloropropane 50 49 98 81-116 # Column to be--u-s-e-d to ag recovery and RPD values wit an asterisk * Values outside of QC limits COMENTS: page 1 of 6 FORM III VOA FORM 3 WATER VOLATILE LAB CONTROL SAMPLE Lab Name: MITKEM.CORPORATION Contract: Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 Matrix Spike - Sample No. : V2VLCS SPIKE SAMPLE LCS LCS QC. ADDED CONCENTRATION CONCENTRATION k LIMITS COMPOUND (ug/L) (ug/L) (ug/L) REC ## REC. ----------- ------------- ------------- ------ --------- Dibromomethane 50 49 98 86-124 Bromodichloromethane 50 54 108 90-114 cis-1,3-Dichloropropene 50 54 108 78-119 4-Methyl-2--pentanone 50 45 90 57-138 Toluene 50 47 94 81-121 trans-1,3-Dichloroprope 50 56 112 85-118 1, 1,2-Trichloroethane 50 48 96 44-159 1,3-Dichloropropane 50 51 102 79-125 Tetrachloroethene 50 45 90 73-121 2-Hexanone 50 47 94 53-145 Dibromochloromethane 50 58 116 80-124 1, 2-Dibromoethane 50 46 92 80-124 Chlorobenzene 50 46 92 82-118 1, 1, 1,2-Tetrachloroetha 50 56 112 84-121 Ethylbenzene 50 42 84 80-122 Xylene (Total) 150 130 87 81-121 Styrene 50 44 88 77-128 Bromoform 50 50 100 77-130 Isopropylbenzene 50 44 88 58-148 1,1,2,2-Tetrachloroetha 50 43 86 76-125 Bromobenzene 50 49 98 76-124 1,2,3-Trichloropropane 50 48 96 57-140 n-Propylbenzene 50 44 88 72-119 2-Chlorotoluene 50 46 92 75-120 1,3, 5-Trimethylbenzene 50 40 80 76-116 4-Chlorotoluene 50 47 94 78-116 tert-Butylbenzene 50 45 90 71-115 1,2,4-Trimethylbenzene 50 40 80 77-117 # Column to be used to flag recovery and RPD values with an asterisk * Values outside of QC limits CONZE3NTS: page 2 of 6 FORM III VOA FORM 3 WATER VOLATILE LAB CONTROL SAMPLE Lab Name: MITKEM CORPORATION Contract: Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 Matrix Spike - Sample No. : V2VLCS SPIKE SAMPLE LCS LCS QC_ ADDED CONCENTRATION CONCENTRATION o LIMITS COMPOUND (ug/L) (ug/L) (ug/L) REC # . REC. --------- --------- ------------- -------- - ______ ______ sec-Butylbenzene 50 41 82 67-117 4-Isopropyltoluene 50 45 90 68-118 1,3-Dichlorobenzene 50 51 102 80-116 1,4-Dichlorobenzene 50 49 98 80-114 n-Butylbenzene 50 41 8.2 58-121 1, 2-Dichlorobenzene 50 50 100 81-116 1,2-Dibromo-3-chloropro 50 48 96 71-126 1, 2,4-Trichlorobenzene 50 39 78 67-114 Hexachlorobutadiene 50 42 84 50-111 Naphthalene 50 44 88 .58-133 1,2,3-Trichlorobenzene 50 39 78 64-118 # Column to be used to flag recovery and RPD values with an asterisk * Values outside of QC limits COMMENTS: page 3 of 6 FORM III VOA ;r FORM 3... WATER; VOLATILE LAB CONTROL SAMPLE t. Lab Name: MITKEM .CORPORATION Contract: Lab Code: MITKEM Case No. SAS -No. : SDG No. : MD0751 Matrix Spike - Sample No. : V2VLCS SPIKE I LCSD LCSD ADDED CONCENTRATION o o QC LIMITS. COMPOUND (ug/L) (ug/L) REC # RPD # RPD REC. Dichlorodifluoromethane 50 51 102 2 40 48-135 Chloromethane 150 42 84 2 40 60-118 Vinyl Chloride 50 46 92 2 40 65-113 Bromomethane j50 43 86 0 40 73-122 Chloroethane 50 46 92 0 40 72-118 Trichlorofluorometha.ne 50 40 80 14 40 68-129 1,-I-Dichloroethene 50 42 84 5 40 67-121 Acetone 50 53 106 6 40 38-161 Iodomethane 50 57 114 2 40 72-130 Carbon Disulfide 50 Methylene Chloride 50 48 96 4 40 59-132 trans-1,2-Dichloroethen 50 44 88 2 40 71-124 I Methyl tert-butyl ether 50 52 104 2 40 75-123 1,1-Dichloroethane 50 48 96 4 40 83-116 Vinyl—acetate 50 45 90 2 40 44-160 2-Butanone 50 47 94 0 40 64-139 cis-1,2-Dichloroethene 50 45 90 2 40 83-120 2,2-Dichloropropane 50 53 106 4 40 70-129 Bromochloromethane 50 57 114 2 _ 40 85-124 Chloroform 50 50 100 4 40 89-118 Tetrahydrofuran 50 50 100 0 40 76-126 1,1,1-Trichloroethane 50 47 94 .4 40 81-122 1,1-Dichloropropene 50 47 94 0 40 76-122 Carbon Tetrachloride 50 50 100 4 40 79-125 1,2-Dichloroethane 50 53 106 6 40 83-123 Benzene 50 50 100 2 40 81-120 Trichloroethene 50 55 110 5' 40_._. 77_-121_ 1,2-Dichloropropane 50 .�8 96 2 40 81-116 # Column to be used to flag recovery and RPD. values with an asterisk * Values outside of QC limits COMMENTS: page 4 of 6 FORM III VOA FORM 3 WATER VOLATILE LAB CONTROL SAMPLE Lab Name: MITKEM CORPORATION Contract: Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 Matrix Spike - Sample No. : V2VLCS SPIKE LCSD LCSD ADDED CONCENTRATION % °s QC LIMITS COMPOUND (ug/L) (ug/L) REC # RPD # RPD REC. ------------------------ --------- ------------- ------ ------ ------ ------ ------------------------ --------- ------------- ------ ------ ------ ------ Dibromomethane 50 49 98 0 40 86.-124 Bromodichloromethane 50 52 104 4 40 90-114 cis-1,3-Dichloropropene 50 53 106 2 40 78-119. 4-Methyl-2-pentanone 50 46 92 2 40 57-138 Toluene 50 47 94 0 40 •81-121 trans-1,3-Dichloroprope 50 55 110 2 40 85-118 1,1,2-Trichloroethane 50 47 94 2 40 44-159 1,3-Dichloropropane 50 50 100 2 40 79-125 Tetrachloroethene 50 45 90 0 40 73-121 2-Hexanone 50 50 100 6 40 53-145 Dibromochloromethane 50 55 110 5 40 80-124 1,2-Dibromoethane 50 46 92 0 40 80-124 Chlorobenzene 50 45 90 2 40 82-118 1,1,1,2-Tetrachloroetha 50 54 108 4 40 84-121 Ethyl-benzene 50 43 86 2 40 80-122 Xylene (Total) 150 130 87 0 40 81-121 Styrene 50 44 88 0 40 77-128 Bromoform 50 50 100 0 40 77-130 Isopropylbenzene 50 44 88 0 40 58-148 1,1,2,2-Tetrachloroetha 50 44 88 2 40 76-125 Bromobenzene - 50 48 96 2 40 76-124 1,2,3-Trichloropropane 50 49 98 2 40 57-140 n-Propylbenzene 50 44 88 0 40 72-119 2-Chlorotoluene 5.0 48 96 4 40 75-120 1,3,5-Trimethylbenzene 50 40 80 0 40 76-116 4-Chlorotoluene 50 47 94 0 40 78-116 tert-Butylbenzene 50 44 88 2 40 71-115 1,2,4-Trimethylbenzene 50 41 82 2 40 77-117 # Column to be used to flag recovery and RPD values with an asterisk * Values outside of QC limits COMMENTS: page 5 of 6 FORM III VOA FORM 3 WATER VOLATILE LAB CONTROL SAMPLE Lab Name: MITKEM CORPORATION Contract: Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 Matrix Spike - Sample No. : V2VLCS SPIKE LCSD LCSD ADDED CONCENTRATION a o QC LIMITS COMPOUND (ug/L) (ug/L) REC # RPD # RPD REC. ------------------------ ---------- ------------- ------ ------ ------ ------ sec-Butylbenzene 50 40 80 .2 40 67-117 4-Isopropyltoluene 50 44 88 2 40 68-118 1,3-Dichlorobenzene 50 50 100 2 40 80-116 1,4-Dichlorobenzene 50 48 96 2 40 80-114 n-Butylbenzene 50 41 82 0 40 58-121 1,2-Dichlorobenzene 50 48 96 4 40 81-116 1, 2-Dibromo-3-chloropro 50 53 106 10 40 71-126 1, 2,4-Trichlorobenzene 50 41 82 5 40 67-114 Hexachlorobutadiene 50 41 82 2 40 50-111 Naphthalene 50 48 96 9 40 58-133 1,2,3-Trichlorobenzene 50 41 82 5 40 64-118 # Column to be used to flag recovery and RPD values with an asterisk' * Values outside of QC limits RPD: 0 out of 67 outside limits Spike Recovery: 0 out of 134_ outside limits COMMENTS page 6 of 6 FORM III VOA FORM 3 WATER VOLATILE LAB CONTROL SAMPLE Lab Name: MITKEM CORPORATION Contract: Lab Code: -MITICEM Case No. : SAS No. : SDG No. : MD0751 Matrix Spike - Sample No. : V2VLFB SPIKE SAMPLE LCS LCS ADDED CONCENTRATION CONCENTRATION a LIMITS COMPOUND (ug/L) (ug/L) (ug/L) REC # REC. Vinyl Chloride 1 0. 9 90 80-120 1,1-Dichloroethene 1 0. 9 90 80-120 # Column to be used to flag recovery and RPD values with an asterisk * Values outside of QC limits R:PD: 0 out of O outside limits Spike Recovery: 0 out of 2 outside limits COM ENTS: FORM III VOA U-S_ EPA - CLP 5A EPA SAMPLE NO SPIKE SAMPLE RECOVERY - - -- -- mw-107 Lab Name: Mitkem Corporation Contract: 28367-0110- Lab Code: MITKEM Case No. SAS No. : SDG No. : MD0751 Matrix (soil/water) : WATER Level (low/med) : MED % Solids for Sample: 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L Control----- --- j -------- ! Limit Spiked Sample i Sample Spike Analyte ! %R Result (SSR) C ! Result (SR) C Added (SA) I %R Q M Antimony 75-125 437.9260i 20.0000 U ! 455.50 96. 1 P 'Arsenic 75-125 497.2000 24 ..1778 � !!' 455.50 ! 103.8" P jBarium 75-125 9663-42601 200.0000 Ui 9100.00 1 106.2•. P !Beryllium 7.5-125 236.3334 i j 5.0000 U 227.00 ' 104_1: P 'Cadmium 75-125 232.0381 5.0000 I'I U 1 227.00 102.2= P- jChromium 75-125 - 924 .0672 i 20.0000IU 910.001 101.5' P JLead 75-125 479.4028 1 1 10.0000 U 455.00 I 105.4* P flNickel i 75-125 2311.1327 50.00001U ' 2270-00 ; 101.8s PI !Selenium 75-125 446-6928 30-0000 ! U1 455.00 98.2; ' P 'Silver 75-125 1066.5397 20_0000 U ' 1130.00 i 94 . 4 P iThallium 1 75-125 452.7829 20.0000 ! U j 955.00 99.5 i P (Vanadium i 75-125 2387. 6322 5fl_0000 i U 2270.00 105.21 P Zinc 75-125 2329.7269 ! 1 50.0000 U i 2270-00 I 102.6' P Comments: FORM V (Part 1) - .IN SW846 U.S. EPA - CLP 6 EPA SAMPLE NO DUPLICATES MW-107 Lab Name: Mitkem Cor oration Contract 28367-0110- i Lab Code: MITKEM Case No_ SAS No. : - SDG No_ : MD0751 Matrix (soil/water) : WATER Level (low/med) MED Solids for Sample: 0_0 % Solids for Duplicate: 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L Control Analyte Limit Sample (S) C , Duplicate (D) C . ' 1 RPD Q M Antimony 20.0 20.0000 U I 20.0000', U ! p Arsenic 20.0 ! 24. 1778 25.7027 6_is P Barium 200.0 200.0000 U = 200.0000U p , Beryllium 5.0:' 5.0000 U 5.0000= U ; p Cadmium 5.01 5.0000 U 5.0000 U p Chromium 20.01 20.0000 ` U 20.0000; U ` p Lead 10.0 10.0000 U ° 10.0000 U ` p Nickel 50.01 50.0000 U SO.0000 U p Selenium 30.01 30.0000 U 30.0000! U s _ P Silver 20.0 20.0000 U 1 20.0000 U ' s P Thallium 20.0 20.0000 U ; 20.0000 U € p Vanadium 50.0 50.0000 U ` 50_0000 U = p Zinc 50.0; 50.0000 ` U ' 50_0000 U + ` P FORM VI - IN SW846 4A EPA SAMPLE NO. VOLATILE METHOD BLANK SU"AARY VBLK2V Lab Name: MITKEM CORPORATION Contract: Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 Lab File ID: V2G9182 Lab Sample ID: MB-18759 Date Analyzed: 06/28/05 Time Analyzed: 1215 GC Column: DB-624 ID: 0.25 (mm) Heated Purge: (Y/N) N Instrument ID: V2 THIS METHOD BLANK APPLIES To THE FOLLOWING SAMPLES, MS and MSD: EPA LAB LAB TIME SAMPLE NO SAMPLE ID FILE ID ANALYZED --- -------------- ---------- 01 V2VLFB LFB-18759 V2G9184 1308 02 V2VLCS LCS-18759 V2G9185 1350 03 V2VLCSD LCSD-18759 V2G9186 1416. 04 TB D0751-09A V2G9190 1613 05 B-107 D0751-04B V2G9195 1827 06 MW-107 D0751-05B V2G9196 1853 07 08 09 10 11 - 12 - 13 14 ' 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 CONIlK=S: page 1 of 1 FORM IV VOA OLM03.0 lA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: MITKEM CORPORATION Contract: VBLK2V Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 Matrix: (soil/water) WATER Lab Sample ID: MB-18759 Sample wt/vol: 5.000 (g/mL) ML Lab File ID: V2G9182 Level: (low/med) LOW Date Received: Moisture: not dec. Date Analyzed: 06/28/05 GC Column: DB-624 ID: 0.25 (mm) Dilution Factor: 1.0 Soil Extract Volume: _(uL) -Soil Aliquot Volume: (U,) CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q 75-71-8---------Dichlorodifluoromethane 5 U 74-87-3---------Chloromethane 5 U 75-01-4---------Vinyl Chloride 1 U 74-83-9---------Bromomethane 51 U 75-00-3---------Chloroethane 5 U 75-69-4---------Trichlorofluoromethane 5 U 75-35-4---------1,1-Dichloroethene T 1 U 67-64-1---------Acetone 5 U 74-88-4---------Iodomethane 5 U 7.5-15-0---------Carbon Disulfide 5 U 75-09-2---------Methylene Chloride 5 U 156-60-5--------trans-1,2-Dichloroethene 5 U 1634-04-4-------Methyl tert-butyl ether 5 U 75-34-3---------1,1-Dichloroethane 5 U 108-05-4--------Vinyl acetate 5 U 78-93-3---------2-Butanone 5 U 156-59-2--------cis-1,2-Dichloroe ene 5 U 590-20-.7--------2,2-Dichloropropane 5 U 74-97-5---------Bromochloromethane 5 U 67-66-3---------Chloroform 5 U 109-99-9--------Tetrahydrofuran 5 U 71-55-6---------1,1,1-Trichloroethane 5 U 563-58-6---------1,1-Dichloropropene 5 U 56-23-5---------Carbon Tetrachloride 5 U 107-06-2--------1,2-Dichloroethane 5 U 71-43-2---------Benzene 5 U 79-01-6---------Trichloroethene 5 U 78-87-5---------1,2-Dichloropropane 5 U 74-95-3---------Dibromomethane 5 U 75-27-4---------Bromodichloromethane 5 U 10061-01-5------cis-1,3-Dichloropropene 5 U 108-10-1--------4-Methyl-2-pentanone 5 U 108-88-3--------Toluene 5 U 10061-02-6------trans-1,3.-Dichloropropene 5 U FORM I VOA OLM03.0 ti-'- lA EPA SAMPLE NO, VOLATILE ORGANICS ANALYSIS DATA SHEET VBLK2V Lab Name: MITKEM CORPORATION Contract: Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 Matrix: (soil/water) WATER Lab Sample ID: MB-18759 Sample wt/vol: 5.000 (g/mL) ML Lab File ID: V2G9182 Level: (low/med) LOW Date Received: Moisture: not dec. Date Analyzed: 06/28/05 GC Column: DB-624 ID: 0.25 (mm) Dilution Factor: 1.0 Soil Extract Volume: _ (uL). Soil Aliquot Volume: (uL) CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q 79-00-5---------1, 1,2-Trichloroethane 5 U 142-28-9--------1,3-Dichloropropane 5 U 127-18-4--------Tetrachloroethene 5 U 591-78-6--------2-Hexanone 5 U 124-48-1--------Dibromochloromethane 5 U 106-93-4--------1,2-Dibromoethane 5 U 108-90-7--------Chlorobenzene 5 U 630-20-6--------1, 1,1,2-Tetrachloroethane 5 U 100-41-4--------Euhylbenzene 5 U ----------------m,p-Xylene - 5 U 95-47-6---------o-Xylene 5 U 1330-20-7-------Xylene (Total) 5 U 100-42-5--------Styrene 5 U 75-25-2---------Bromoform 5 U 98-82-8---------Isopropylbenzene 5 U 79-34-5---------1, 1,2,2-Tetrachloroethane 5 U 108-86-1--------Bromobenzene 5 U 96-18-4---------1,2,3-Trichloropropane 5 U 103-65-1--------n-Propylbenzene 5 U 95-49-8---------2-Chlorotoluene 5 U 108-67-8--------1, 3, 5-Trimethy zene 5 U 106-43-4--------4-Chlorotoluene 5 U 98-06-6---------tert-Butylbenzene 5 U 95-63-6---------1,2,4-Trimethylbenzene 5 U 135-98-8--------sec-Butylbenzene 5 U 99-87-6---------4-Isopropyltoluene 5 U 541-73-1--------1,3-Dichlorobenzene. 5 U 106-46-7--=-----1,4-Dichlorobenzene 5 U 104-51-8--------n-Butylbenzene 5 U 95-50-1---------1,2-Dichlorobenzene 5 U 96-12-8----------1,2-Dibromo-3-chloropropane_ 5 U 120-82-1--------1, 2,4-Trichlorobenzene 5 U 87-68-3---------Hexachlorobutadiene 5 U 91-20-3---------Naphthalene 5 U FORM I VOA 012403. 0 IA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: MITKEM CORPORATION Contract: VBLK2V Lab Code: MITKEM Case No. : SAS No. : SDG No. : MD0751 Matrix: (soil/water) WATER ' Lab Sample ID: MB-18759 Sample wt/vol: 5.000 (g/mL) ML Lab File ID: V2G9182 Level: (low/med) LOW Date Received: OW Moisture: not dec. Date Analyzed: 06/28/05 GC Column: DB-624 ID: 0.25 (mm) Dilution Factor: 1.0 Soil Extract Volume: (uL) Soil Aliquot Volume: (uL) CONCENTRATION UNITS: CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q -87-61-6----------1,2,3-Trichlorobenzene 5 U 60-29-7---------Ether 5 U 108-20-3--------Diisopropyl Ether_ 5 U 637-92-3--------Ethyl tert-butyl ether_ 5 U 994-05-8--------tert-Amyl methyl ether 5 U -91-1--------1,4-Dioxane 100 U --FORM I VOA OLM03.0 U.S_ EPA - CLP 3 BLANKS Lab Name: Mitkem Corporation Contract: 28367-0110-00000 Lab Code: MITKEM Case No. SAS No. : SDG No. : MD0751 Preparation Blank Matrix (soil/water) : WATER Preparation Blank Concentration Units (ug/L or mg/kg) : UG/L I ± Initial -- I ( i � i Calib. Continuing Calibration Prepa- Blank Blank (ug/L) ration ! j Analyte (ug/L) C 1 C 2 C 3 C - Blank C ! M !Antimony 5.81 B 5.4 B 5.9 B ! 5.2 : B 1.200 U ! ! Arsenic 1.6i U 1.7 ' B - -2.0 B 1.6 U - 1.600: U ,Barium 3.21 B ! 3.7 B 2.1'; U 2.1 U 3.113! B (Beryllium 0.21 U 0_1 U 0.11 U 0.2 - B 0.150+ U !Cadmium 0.1; U 0.1 B : 0_l i U 0.1 B 0.100; U !Chromium 0.4 U 0.4 U 0.411 U 0.4 U 0.637 B i jLead 0.5I U 1.2 _ B ; 0.7! B : 0.5 ' U 0.460j U (Nickel 1.01 B 1.6 B 0.6; U 1.1 B 0.654 B ;Selenium ' 1.U U I 1.5 B ' 1.0 U 1.0 - U , 1.870! B iSilver i 8.6 B I 6.5 B 1.3! B 0.9 - U : 24.0311 B I Thallium 2.31 B 2.0 * B : 1.2 U 1.2 U 1_200 U lVanadium 0.7J1J B 1.1 : B 0.6: B 0.8 B . . 0.970j U Zinc 17.4 B I 11.9 B 2.7; B 5-1 - B ^ 16.9381 B I i FORM III - IN SW846 U-S. EPA - CLP 3 BLANKS Lab Name: Mitkem Cor oration Contract: 28367-0110-00000 Lab Code: MITKEM Case No- SAS No- : SDG No. : MD0751 Preparation Blank Matrix (Soil/water) : Preparation Blank Concentration Units' (ug/L or mg/kg) :. Initial j Calib. Continuing Calibration_ I � Prepa- + Blank Blank (ug/L) ! i ration Analyte (ug/L) C 1 C 2 C 3 C ! Blank C ` j M ,Antimony ( ---- 4-9 ! B 3_8' B -- I pJ Arsenic I 1.6 i U i 2-4 B t - p :Barium - 3-3 ; B I 2.3: B : P ;Beryllium + 0.1 i U i 0.1= U : P - I icadmium 0.1 U 0.1; U ; p Chromium 0-4 U 0-4' U ! i p Lead ' 0-5 U 0_S, U i ! p Nickel I 0.8 B 1._2' B p (Selenium 1-0 I U 1-0, U I i ! p j Silver i 0.9 U 0-9' U p !Thallium 1.2 ! U.j 2.1' B i c p Vanadium I 1.1 B i 0_9 B I I I € ! P ;Zinc I 3..8 i B I 5-9 B i I i P 4 FORM III - IN SW846 O.S. EPA - CLP 3 BLANKS Lab Name: Mitkem Coloration Contract: 28367-0110-00000 Lab Code: MITKEM Case No. SAS''No. : SDG No. : MD0751AG Preparation Blank Matrix .(soil/water) : WATER Preparation Blank Concentration Units (ug/L or mg/kg) : UG/L Initial Calib. Continuing Calibration Prepa- Blank Blank (ug/L) ration Analyte (ug/L) C 1 C 2 C 3 C Blank C M Silver 2.2 B -- 0.9 0.91 II 0.9 U 0.910 U 1 -[ FORM III - IN SW846 U.S. EPA - CLP 3 BLANKS Lab Name: Mitkem Corporation Contract: 28367-0110-00000 Lab Code: MITKEM Case No. SAS No. : SDG No: : MD0751AG Preparation Blank Matrix (soil/water) : Preparation Blank Concentration Units (ug/L or mg/kg) : Initial Calib. Continuing Calibration iFepa- Blank Blank (ug/L) ration Analyte (ug/L) C- 1 C 2 C 3 C Blank C M 'Silver 0.9 _�. - �. P t SW84b FORM III -` IN 8A VOLATILE" INTERNAL STANDARD AREA AND RT SUMMARY Lab Name: MITKEM CORPORATION Contract: Lab Code: MITKEM Case No_ : SAS No. : SDG No. : MD0751 Lab File ID (Standard) : V2G9181 Date Analyzed: 06/28/05 Instrument ID: V2 Time Analyzed: 1126 GC Column: DB-624- ID: 0.25 (mm) Heated Purge: (YIN) N IS1 IS2 CBZ IS3 (DCB AREA # RT # AREA # RT # AREA # RT # ---- ------- ---------- ------- ---------- ------- 12 HOUR STD 1127068 6.59 717578 10.29 350740 13.17 UPPER LIMIT 2254136 7.09 1435156 10.79 701480 13.67 LOWER LIMIT 563534 6.09 358789 9.79 175370 12.67. ------- ---------- ------- ---------- ------- EPA SAMPLE NO. ---- ------- ---------- ------- ---------- ------- 01 VBLK2V 1048240 6.59 657033 10.29 245503 13.17 02 V2VLFB 1027674 6.58 656274 10.29 251835 13.17 03 V2VLCS 1071211 6.59 694000 10.29 340685 13.17 04 V2VLCSD 1092909 6.59 707304 10.29 344046 13.17 05 TB 973386 6.59 688638 10.30 282681 13.17 06 B-107 959450 6.59 712663 10.30 352806 13.17 07 MW-107 1010370 6.59 732478 10.30 364361 13.17 08 09 _ 10 11 - - -- - 12 13 14 - 15 16 17 18 19 20 2.1 - - - 22 - - IS1 = Fluorobenzene IS2 (CBZ) = Chlorobenzene-d5 IS3 (DCB) = 1,4-Dichlorobenzene-d4 AREA UPPER LIMIT = +10016 of internal standard area AREA LOWER LIMIT = - 500 of internal standard area RT UPPER LIMIT = + 0.50 minutes of internal standard RT RT LOWER LIMIT = - 0.50 minutes of internal standard RT # Column used to flag values outside QC limits with an asterisk. * Values outside of QC limits. page 1 of 1 FQ M VIII VOA OLM03.0 cn C) r) > 4t > rrl tri 1-4 ,,,r,,)A�tmc" Az: ,,,c', Fla-- C3 M a 0 00 1 0 (3 - — --i G D 0 o 0 O 0 co c" 0 tri 0 0 1,� N SKI, > > G O 0 Q to 12:11 co COMPOSITE El ry z NAg Y GRAB -1 CL10 -,�01,> - C. ,�, tj 0 00 0 x �K WATER col Ul tri__ 'K 0 �71 IV SOIL z %0 v.a a - - 0 0 1, OTHER C7 cj Qr O k > >—P ? - E3 OF CONTAINERS 0> > 0 6-5 � in 0 T1 ci 400 Y > rri 10 lot rn En 0 > > z > X OM > U3 c CD 0 t7� 0 t,y t3j Pd MITKEM CORPORATION Sample Condition Form Page I of Received By: Reviewed By: Date: U76-7/�OS- MITKEM Project#: PO 71-1) Client Project: Client: 7rF-� Soil Headspace Preservation(pH VOA or Air Bubbles Lab Sample ID HNO3 H,SO, HCl NaOH Matrix > 1/4" Cooler Sealed Yes I oNo ' C) Z, 14 1)Custody Seal(s) esent I A b e nt 0-3 ZZ C00le 1%Botles 1)4 47 Intact/Bro '47- 1 n -'e-7- 2)Custody Seal Number(s) D --7 & Z Tom' 3) Chain-of-Custody (�PPDrese t/Absent t)Cooler Temperature Coolant Condition Tu- 3)Airbill(s) Present I Aj�g�pi Airbill N umber(s) i)Sample Bottles (n:tac roken/Leakin Date Received -1 h" 1)Time Received VOA Matrix Key:_ US = Unpreserved Soil A=Air 3reservative,Name/Lot No: UA= Unpreserved Aqueoi H = HCI MIN= MeOH & NaHSO4 E = Encore N = NaHSO4 M =MeOH See Sample Condition Notification/Corrective Action Form yes I no Rad OK yes/no orm ID: SampleCond.Form-1 1/04